GCMS analysis results, sample AE12534, June 2002

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Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052902\12534.D Vial: 25 Acq On : 30 May 2002 5:37 am Operator: McLean Sample : gc/ms scan 5/28 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 6 Propiolonitrile Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 4.02 . 1.47 ug/L 932035 1,4-Dichlorobenzene-d4 9.90

Hit# of 5 Tentative ID MW MolForm CAS# Qua 1 Propiolonitrile 51 C3HN 001070-71-9 4 2 Pent-4-enylamine 85 C5H11N 022537-07-1 2 3 1,1,2-Trifluoroethane 84 C2H3F3 000430-66-0 1 4 2-p-Nitrobenzoyl-l,3,5-tribenzyl... 569 C33H31NO8 1000129-85-6 1 Abundance Scan 161 (4.025 min): 12534.D (-159) (-) m/z 51.10 100.00%| 51

84 88 5000

42 । 1 ‘ ।' ■ ■ ■ । ■1' i '1 '11 '1 1 3.60 3.80 4.00 4.20 4.40 Of ■ ■ I •»। < i > • ■ > । f l • ■.1 > i “ “ i • < > * j ■ ■ ■ • 36 (■ I ■ 11 ■ • । u /1 “‘—0080’010 m/z 88.00 54.12% 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95

MMHMAwaindl Tl/Z-> Abundance #12371: Propiolonitrile 51

5000 3.60 3.80 4.00 4.20 4.40 m/z_ 84.00 51.90

miz-> 0 5+12.18,428,32. 38,447 T"[emmm. 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #745: Pent-4-enylamine 30 1’1*+I+1171114’ r'11 • » i * • 3.60 3.80 4.00 4.20 4.40 50001 m/z 42-10 21.87% 39 43 56 27 04 i1 “ ■ i Ir l 111/11146.59537—,.. 63 6770 TTTTIWTTTTTTTTWTTTTT 84 niz-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #12369:1,1,2-Trifluoroethane 51 3.60 3.80 4.00 4.20 4.40 1 m/z 84.95 18.91% 5000 33 45 65

n/z—> 01 19 26 M9.H mm 11 12)1 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 69 8134 010000020202102020000120002277 3.60 3.80 4.00 4.20 4.40

12534.D 052202.M Mon Jun 03 11:46:33 2002 Page 9

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