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GCMS analysis results, sample AE12288, June 2002

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Gas chromatography mass spectrometry results for sample AE12288 including surrogate recovery data analyzed on June 7, 2002.

NYC-WTC_000014189–000014213

Folder label: “GCMS X 5/24/02 A 5/29/02

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NYC 9/11 Public Portal Document ULDLCLY DEaLtil oupOULIC KCPOL L

Data File : C:\MSDCHEM\l\DATA\052902\12288.D Vial: 7 Acq On : 29 May 2002 2:58 pm Operator: McLean Sample : gc/ms scan 5/24 fb Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ******************************** * * *********************************** Peak Number 14 Anthracene, 2 -methyl - Concentration Rank.14

R.T. EstConc Area Relative to ISTD R.T. 22.54 0.25 ug/L 262755 Phenanthranerie-dl0 22.91 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Anthracene, 2-methyl- 192 C15H12 000613-12-7 53 2 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 42— 3 4-Hydroxy-3,5-dimethylcinnamic acid 192 C11H1203 1000132-15-8 38 4 2-Imidazolidinone, 1-methoxy-3-p... 192 C10H12N2O2 052420-43-6 37 Abundance Scan 3312 (22.539 min): 12288.D (-3304) (-) m/z 192.10 100.00% 192

5000

82 36 146 160 ...... y........ 22.20 22.40 22.60 22.80 49 70 I 120 132 0 mLHH ■ • i “ " I “ “ 111" i ...... H m/z 191.10 22.84% Wz-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #125845: Anthracene, 2-methyl- 192

5000 22.20 22.40 22.60 22.80 m/z96.00 15.52% 67 75 88 9 115 126 139 152 165 176 0- Tm??1mTTTTmmmm trrp nfe-> 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80953:2-Propenal, 3-(3,4-dimethoxypheny!)- 192 161 2220 22.40 22.60 22.80U 5000 m/z 193.00 14.95% 77 91 121 149 177 52 64 138

niz-> 0- .. I I ’ ‘ ‘* I ’ HH 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 -

Abundance #81030:4-Hydroxy-3,5-dimethylcinnamic acid .................. • ‘ I ’ ‘ ‘ * I ’ ‘ ‘ i ■ 1 ' ■ i ■ ■ TT 192 22.20 22.40 22.60 22.80 m/z 146.10 14.71% 5000

89 175 — 45 55 631 77 117 I 145 135 |, 163 m/z-> 1 97 105 0 -+-++++*44++44lTp’t HTHp 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 4 0 22.20 22.40 22.60 22.80

12288.D 052202.M Mon Jun 03 09:37:15 2002 Page 17

NYC-WTC_000014210

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NYC-WTC_000014210Source: NYC Law Department, mirrored locally

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