GCMS unknowns report, DEP Box 15, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report • ' Data File : C:\HPCHEM\1\DATA\MAY2902\12164.D Vial: 7 Acq On : 29 May 2002 5:14 pm Operator: Morgan Sample : gc/ms scan 5/23 Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0528.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 Phenanthrene-diO Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 25.56 0.46 ug/1 53317 Phenanthrene-dl0 25.42 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Phenanthrene-diO 59 188 C14D10 001517-22-2 38 2 -(4-Tolyl/-3-methyl-pyrazol-5-one 188 C11H12N2O 035496-19-6 38 3 Pentacyalo[8.4.0.0(3,7).0(4,14).0(6 188 C14H20 000000-00-0 33 4 Anthracene-d10- 188 C14D10 001719-06-8 32 Abundance 7 Scan 2235 (25,560 min): 12164.D (-) m/z 188.10 100.00% 188

5000

T 49 y 8P 7 160 /* .. ' ■ i ' ■ ■ ■ i ‘ — pij j P j > । J । ! > ) > ■ i 253 268 TT 25.20 25.40 25.60 25.80 m/z 94.00 21.27% I"

miz-> 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #19958: Phenanthrene-d10 108

5000 25.20 25.40 25.60 25.80 m/z 189.10 18.02% 80 94 160 66 niz-s 40 60 80 1.,=..1 I'l.... I.... 100 120 140 160 180 200 220 240 260 Abundance #19863: -(4-Tolyl)-3-methyl-pyrazol-5-one 188 91 25,20 25.40 25.60 25.80 105 m/z 80.00 14.20% 5000 119 65 -TO I 78 I ’lrr2//0/n//Trt 4T1 TIndno,—146 mmTT ■ ‘ I ' ‘ ' i 1 ' “ ■ i ■ ■ • ■ i 1 1 miz-> 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #19959: Pentacyclo[8.4.0.0(3,7).0(4,14),0(6,11)]tetradecane ■ i ■ ■ ■ ■ i ■ ■ r i ■ • ■ ■ i ■ ■ • ' i ■ 188 25.20 25.40 25.60 25.80 m/z 184.10 ------ 1 | I . I / , F| 1 14.11% 5000

79 92 106117 131 145 I?® 173 ----- •।•••■।• ' ■ i ■ ■ ■ ' i ' 1 1 ■ i ■ ■ ■ ■ i ■ • ' ■ i ■ ■ ‘ ■ i ■ m/z—> 40 60 80 100 120 140 160 180 200 220 240 260 25.20 25.40 25.60 25.80

12164.D GCMS0528.M Thu May 30 08:42:18 2002 Page 2

NYC-WTC_000013814