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GCMS blank analysis, sample AE01639, March 2002

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Gas chromatography-mass spectrometry blank analysis for sample AE01639 completed March 21, 2002, with all organic compound detections below minimum detection limits.

NYC-WTC_000012083–000012093

Folder label: “GCMS X 3-1-02 A 3-20-02 MANY RERNNS

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NYC 9/11 Public Portal Document

Library Search Compound Report

. Data File : C:\MSDCHEM\1\DATA\031902\301LB.D Vial: 20 • Acq On : 20 Mar 2002 4:50 am Operator: McLean Sample : RE-INJ 3/1 Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1\5973N\5080302.M (RTE Integrator) Title : Quantitation For Method 508gcscan Library : C:\DATABASE\WILEY7N.L

Peak Number 4 TETRACOSAMETHYLCYCLODODECAS. . . Concentration Rank 4

R.T. EstConc Area Relative to ISTD R.T.

20.28 0.42 ug/L 168187 Acenaphthene-dl0 18.13

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 TETRACOSAMETHYLCYCLODODECASILOXA. . . 888 C24H72O12Sil2 018919-94-3 72 2 n-Nonadecanoic acid, pentamethyl... 428 C24H52O2Si2 000000-00-0 35 3 lH-Purin-6-amine, [(2-fluorophen... 243 C12H10FN5 074421-44-6 32 4 SILICATE ANION TETRAMER 888 C24H72012S112 000000-00-0 28 Abundance Scan 1897 (20.282 min): 301LB.D (-)i m/z 73.10 100.00% 73

5000

147 221 281 355

401 20.00 20.20 20.40 20.60 s mmmr m/z 355.10 32.63% n/z—> T—50 100 150 200 250 300 350 400 450 500 550 600 650 700 Abundance#391010: TETRACOSAMETHYLCYCLODODECASILOXANE $$ Cyclodo 73 355

5000 147 221 281 • ■ i ■ ■ ‘ ■ i ' 20.00 20.20 20.40 20.60 M...... m/z 147.10 25.07% 415

miz-> 0- ISIgIr pH 1 H —H —+ ।.... i....i.... i. i 0 50 100 150 200 250 300 350 400 450 500 550 600 650 700 Abundance #346318: n-Nonadecanoic acid, pentamethyldisilyl ester 43 355 .................... 20.00 20.20 20.40 20.60 147 m/z 221.10 19.09% 5000 413 203 $3

mz-> 0-T 4 THT 245 295 0 50 100 150 200 250 300 350 400 450 500 550 600 650 700 Abundance #177443: 1H-Purin-6-amine, [(2-fluoropheny!)methyl]- (CAS) .. 73 20.00 20.20 20.40 20.60 m/z 281.00 15.71%

28> 147 221 5000 355 281 429 503

0 Ji L l kkav u i14 ll 44 .+563607 653. 703 ..... . H...... m/z-> 0 50 100 150 200 250 300 350 400 450 500 550 600 650 700 20.00 20.20 20.40 20.60

301LB.D 5080302.M Thu Mar 21 06:35:41 2002 Page 6

NYC-WTC_000012092

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NYC-WTC_000012092Source: NYC Law Department, mirrored locally

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Calibration data for sample AE01639 verifying instrument performance for volatile organic compound analysis on March 21, 2002.

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