GCMS calibration table for TCLP method, March 2002

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Library Search Compound Report

Data File C:\HPCHEM\1\DATA\MAR0102\3381.D Vial: 45 Acq On 3 Mar 2002 7:37 am Operator: Sample gc/ms scan 2/4 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 Phenanthrene-dlO Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

25.85 0.31 ug/1 111470 Phenanthrene-dl0 25.73

Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene-dlO 188 C14D10 001517-22-2 72 2 Anthracene - dl 0 -A1 188 C14D10 001719-06-8 50 3 Antipyrine 188 C11H12N2O 000060-80-0 40 4 - (4-Tolyl) -3-methyl-pyrazol-5-one 188 C11H12N2O 035496-19-6 40 Abundance Scan 2267 (25.851 min): 3381.D (-) m/z 188.10 100.00% 188

5000

80 94

m/z-> Abundance TThT 42 52 i I i I I > I i | I I i ■ 66 -I+ 1801 132 146 140 158 i. I I I I I l ! i ! I J ! [ I J t J J I FI | I I I I j I I J I | I ! ! I | I | I I [ | T P’r FT

30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 + 25.60 25.80 26.00 26.20 m/z 94.00 17.95% #19958: Phenanthrene-dlO 188

5000 25.60 25.80 26.00 26.20 RS 80 941 160 m/z 8 .00 15.19% 00

miz-> •■। । ■ i ■" ■ । ■ TBImImPRTp 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 relljavuyessiyeipan 11 Abundance #19957, Anthracene-ci 188

25.60 25.80 26.00 26.20 5000 m/z 184.10 14.92%

. SO 94 160 T10—mnum—a9Tpe9mmpmpmpgmem m/z—> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #69177: Antipyrine 96 188 25.60 25.80 26.00 26.20 77 m/z 189.10 13.27% 5000 56 31 105

m/z-> 46 — 30 4C)' * 50 ‘ 60 70 80' 90 100 1 0 120 130 140"l5o' 180 170 180 730 ‘ 1 ‘I’ ‘ “ I 145 159 1_____ I 173 □ ................................... 25.60 25.80 26.00 26.20

3381.D GCMS0208.M Mon Mar 25 12:21:11 2002 Page 3

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