GCMS calibration table for TCLP method, March 2002

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Library Search Compound Report

Data File C:\HPCHEM\1\DATA\MAR0102\3381.D Vial: 45 Acq On 3 Mar 2002 7:37 am Operator: Sample gc/ms scan 2/4 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 2 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

8.29 0.29 ug/1 76276 1,4-Dichlorobenzene-d4 12.32

Hit# of 5 entative ID MW MolForm CAS# Qual

1 2-Pentanone, 4 - hydroxy- 4 -methyl - 116 C6H1202 000123-42-2 56 2 5-Hexen-2-one 98 C6H10O 000109-49-9 9

w 3 Morpholine, 4-methyl- 101 C5H11NO 000109-02-4 9 4 4-Penten-2-one, 4-methyl- 98 C6H10O 003744-02-3 7 Abundance Scan 354 (8.290 min): 3381.D (-) m/ z 42.95 :100.00% 43

5000 59 101 ’ rrIT 8.00 8.20 8.40 8.60 m/z-> 10 * "I ‘‘I11 20 30 40 50 +51+ 1 i 1 ' ■ ■ 1 1 • • ■ i ■ ' ■ ■ i • 1 ■ 1 i ■ ■ • ■ i 60 70 80 90 100 110 m/z 59.00 46.85% Abundance #64274: 2-Pentanone, 4-hydroxy-4-methyl- 43

5000 ........................................ 59 8.00 8.20 8.40 8.60 m/z 101.05 2 6.39% 27 I[ . 101 m/z-> • ■ i • ■ r i 1 ' rl n । 1 10 20 30 40 +49+ 50 60 70 80 o4 90 100 110 Abundance.... ... . - k-one 43 ’4I***I*’*I’’’’144’ 8.00 8.20 8.40 8.60 5000 m/z 58.05 17.83% 27 55 15 38 50 83 98 1 • i • • • * i * ■ • > i • • ■ • । • *1**I‘‘ I*I*‘‘-I** 1 1 1 1 1 1 ■ I miz-> 10 20 30 40 50 60 70 80 __ 90 100 110 Abundance ” #63448: Morpholine, 4-methyl- ■ ■ i 1 ■ ■ • i ■ ■ ■ ■ i • ■ ■ ■ i ‘ ■ 43 8.00 8.20 8.40 8.60 m/ z 40,.95 6.22% 5000

71 , 56 I 82 87 93 , • ■ i ■ ■ ■ 1 i 1 1 1 ' i ■ ■ ■ ■ r 1 ' ‘ i ' ‘ 1 ‘ i ‘ 1 ' ' I1 ■ ■ ‘ /" । । । ■ ■ ■ ■ • I । । i । । TITTTTPmmT miz-> 10 20 30 40 _ 50 60 70 80 90 100 110 8.00 8.20 8.40 8.60

3381.D GCMS0208.M Mon Mar 25 12:21:07 2002 Page 2

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