GCMS analysis results for sample AE02721, March 5 2002

NYC 9/11 Public Portal Document

Library Search Compound Report - • Data File : C:\MSDCHEM\1\5973N\02FEB28\02721.D Vial: 6 Acq On : 28 Feb 2002 6:50 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 28, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 4 3-(CYCLOHEX-3'-EN-YL)PROPAN... Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 5.94 0.34 ug/L 134636 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 3-(CYCLOHEX-3'-EN-YL)PROPANOL $$... 174 C8H14O4 015745-87-6 36 2 Acetic acid, 3-[1,3]dioxolan-2-y... 174 C8H14O4 000000-00-0 36 3 N-Ethylformamide $$ N-Formylethy. . . 73 C3H7NO 000627-45-2 9 4 2-Methyl-5-hexen-3-ol 114 C7H140 032815-70-6 9 Abundance Scan 227 (5.936 min): 02721 .D (-) m/z 73.10 100.00% 73

5000 43 1‘141141.a 14**1 87 103 5.60 5.80 6.00 6.20 n/z-> 01..,' n-TT-r.., t. .. 1 'I.. ।. । A ।. ।.. ।.’. ।।.... ।।.... (.... ।.... ।. 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 m/z 43.10 23.58% Abundance #36138:3-(CYCLOHEX-3'-EN-YL)PROPANOL $$ 2-Cyclohexene-1-p... 73

5000 0 5.60 5.80 6.00 6.20 43 m/z 45.10 10.08% 27 55 .1 1,’1—0087 113 174 0- nP TPTmuT ’1—00100—100022210— miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #78238: Acetic acid, 3-[1,3]dioxolan-2-ylpropyI ester 73 - 5.60 5.80 6.00 6.20 5000 m/z 41.10 9.26% 43 27 87 m/z-> 0- mmp 55 THmpnp 113 .i TT—m0pu—E0mmOTT 174 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 Abundance #1794: N-Ethylformamide $$ N-Formylethylamine $$ Formamide... ■ ■ i ' ■ ■ ■ i ■ ' 1 1 i ■ ■ • ■ i ■ ■ ■ ■ i 30 5.60 5.80 6.00 6.20 73 m/z 71.10 6.09%

5000 44 58

15 0 J .... f.'I | | T| I I I 1 | 1 I I | | I I I I | I H I | I | I I | 1 I I I | > I I I | > I 1 | | > ■ ■ i ■ ' ■ ■ i ■ ■ ■ ■ i ■ ' ■ ■ i ' ■ ' ' i miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 5.60 5.80 6.00 6.20

02721.D HP022102.M Fri Mar 01 10:07:52 2002 Page 6

NYC-WTC_000011016