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GCMS analysis results, sample AE02719, March 2002

Machine-extracted title · confidence 68%

Gas chromatography-mass spectrometry analysis of sample AE02719 performed March 5, 2002, reporting other unknown compounds and surrogate 2,4-DDD recovery data.

NYC-WTC_000010987–000011006

Folder label: “GCMS X 2/5/02 A 2/28/02

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NYC 9/11 Public Portal Document

Library Search Compound Report " Data File : C:\MSDCHEM\l\5973N\02FEB28\02719 .D Vial: 4 Acq On : 28 Feb 2002 5:10 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 28, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102 .M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L * * * * * * *************************************************************** Peak Number 11 N-perdeuteriobenzylideneani ... Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 22.28 0.10 ug/L 58931 Phenanthrene-dl0 22.63 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 N-perdeuteriobenzylideneaniline 192 C13D11N 000538-51-2 50 2 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 50 3 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 50 4 8-(3-Hydroxyethyl)-3-methoxybicy... 192 C12H16O2 000000-00-0 47 Abundance Scan 1675 (22.283 min): 02719.D (-) m/z 192.00 100.00% 1912

5000 ........... 2....... / \ 82 96 146 160 22.00 22.20 22.40 22.60 0 - m/ z 191.10 19.12% z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #88409: N-perdeuteriobenzylideneaniline 192

5000 82 T T 188 22.00 22.20 22.40 22.60 54 110 m/z 193.10 16.02% 30 94 160 O' ■■■■I-..!.... ■ ■ i1 ■j ■ i ■ ■ ■ ■ i MHH nmmpmnpmp Tpr n/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #102611:2-Propenal, 3-(3,4-dimethoxypheny!)- $$ Cinnamald... 1912 161 22.00 22.20 22.40 22.60 5000 m/z95.80 13.62% 77 149 89 193 118 64 138 . ............. ......| ...... 0- mmmmm ’1111110010—0371713713 +pr n/z—> 20 30 40 50a) 70 8090 100 110 120 130 140 150 160 170 180 190 200 Abundance #102610:2-Propenal, 3-(3,4-dimethoxypheny!)- (CAS) $$ 3,4.- 192 22.00 22'20' 22.40 22.60 161 m/z 146.00 11.19% 5000 77 149 177 64 89 103 118 138 Illi . Il. 0 “ ’ ‘ I' ’ ‘ 1 “ ’ ‘ l “ “ I ‘1 u ’* I * I I I «« I » I » • I It I I I I J J I I 1 1114 ’ 1’1431*3 .. । n .. 11।।। +e T T i 1 ■ m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.00 22.20 22.40 22.60

02719.D HP022102.M Fri Mar 01 10:07:35 2002 Page 13

NYC-WTC_000011003

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NYC-WTC_000011003Source: NYC Law Department, mirrored locally

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