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GCMS analysis results for sample AE03075, March 5 2002

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Laboratory report documenting gas chromatography-mass spectrometry results for sample AE03075 including surrogate recovery.

NYC-WTC_000010947–000010966

Folder label: “GCMS X 2/5/02 A 2/28/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

' * Data File : C:\MSDCHEM\l\5973N\02FEB28\02717.D Vial: 2 Acq On : 28 Feb 2002 3:30 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 2 8, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 12 1,2-Benzenedicarboxylic aci... Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

24.86 0.06 ug/L 38545 Phenanthrene-dl0 22.63

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 1,2-Benzenedicarboxylic acid, bu... 278 C16H2204 017851-53-5 83 2 Dibutyl phthalate 278 C16H2204 000084-74-2 83 3 Phthalic acid, butyl ester, este... 336 C18H24O6 000085-70-1 83 4 Dibutyl phthalate 278 C16H2204 000084-74-2 74 Abundance Scan 1903 (24.857 min): 02717.D (-) m/z 149.00 100.00% 149

5000 _ -

41 56 86 105 । 205 223 24.60 24.80 25.00 25.20 0----- i i........... . m/z 150.00 10.83% m/z—> :20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #223230:1,2-Benzenedicarboxylic acid, butyl 2-methylpropy... 149

5000 ■ ' I ‘ 1 1 ' I • ‘ i ‘ ‘ i ‘ ' 24.60 24.80 25.00 25.20 m/z41.10 7.83% 27 41 57 76 104 121 205 223 278 0 ----- ‘ f ‘ * I * * ‘ ’ I * ' ' ‘ I ' ‘ ‘ ' I ‘ k ’ 1 1 ‘ ‘ /z—> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #223232: Dibutyl phthalate 149 __ JI___ . 24.60 24.80 25.00 25.20 5000 m/z 223.00 6.08%

29 41 57 76 104 121 163 178 205 223 0- T1*mm*mmp]mmmmmt j i

n/z—> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 Abundance #286375: Phthalic acid, butyl ester, ester with butyl glyc... T T T T 149 24.60 24.80 25.00 25.20 m/Z 205.00 5.28% 5000

57 76 104 121 167 .... 225.223 0-I' 111 11 । ■ । Ai 1111 । 111 ■ । " 111 11 । 278 /z—> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 24.60 24.80 25.00 25.20

02717.D HP022102.M Fri Mar 01 10:07:23 2002 Page 14

NYC-WTC_000010964

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NYC-WTC_000010964Source: NYC Law Department, mirrored locally

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