GCMS reference analysis results for organic contaminants, March 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File : C:\HPCHEM\1\DATA\MAR1902\REF1.D Vial: 4 Acq On : 20 Mar 2002 2:04 am Operator: Sample : gc/ms scan 3/5 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Mar 21 8:32 2002 Quant Results File: GCMS0308.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Mar 08 08:54:27 2002 Response via : Initial Calibration DataAcq Meth : GCMS0308

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.27 152 613118 20.00 ug/1 -0.09 10) Naphthalene-d8 15.90 136 2400618 20.00 ug/1 -0.09 17) Acenaphthene-diO 21.22 164 1282870 20.00 ug/1 -0.09 29) Phenanthrene-diO 25.66 188 1919216 20.00 ug/1 -0.10 38) Chrysene-dl2 33.72 240 1254468 20.00 ug/1 -0.12 44) Perylene-dl2 37.97 264 766249 20.00 ug/1 -0.15

System Monitoring Compounds 37) 2,4-DDD 30.73 235 98139 7.04 ug/mL 0.23 Spiked Amount 5.000 Recovery = 140.80%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.91 74 105125 5.05 ug/1 # 73 3) bis(2-Chloroethyl)ether 11.66 93 235684 7.04 ug/1 90 4) 1,3-Dichlorobenzene 12.17 146 142292 4.11 ug/1 98 5) 1,4-Dichlorobenzene 12.31 146 155745 4.49 ug/1 100 6) 1,2-Dichlorobenzene 12.83 146 166543 5.15 ug/1 98 7) 2,2'-oxybi s(1-Chloropropan 13.15 45 326870 6.93 ug/1 98 8) N-Nitroso-di-n-propylamine 13.53 70 167685 7.69 ug/1 # 86 9) Hexachloroethane 13.67 117 30990 2.39 ug/1 96 11) Nitrobenzene 13.95 77 218508 6.66 ug/1 92 12) Isophorone 14.59 82 486989 7.82 ug/1 99 13) bis(2-Chloroethoxy)methane 15.28 93 296456 7.28 ug/1 96 14) 1,2,4-Trichlorobenzene 15.79 180 142490 5.06 ug/1 97 15) Naphthalene 15.96 128 605029 6.82 ug/1 99 16) Hexachlorobutadiene 16.51 225 22427 1.60 ug/1 98 18) Hexachlorocyclopentadiene 18.70 237 10510 1.21 ug/1 96 19) 2-Chloronaphthalene 19.47 162 367432 6.67 ug/1 96 20) Dimethylphthalate 20.56 163 523333 8.11 ug/1 100 21) 2,6-Dinitrotoluene 20.77 165 109260 6.97 ug/1 # 86 2 2) Acenaphthylene 20.74 152 597868 7.59 ug/1 99 23) Ac enapht hene 21.30 153 407429 7.40 ug/1 98 24) 2,4-Dinitrotoluene 21.94 165 143295 6.83 ug/1 # 78 25) Diethylphthalate 22.69 149 511316 8.16 ug/1 97 26) 4-Chlorophenyl-phenylether 22.84 204 205850 7.67 ug/1 94 27) Fluorene 22.83 166 458559 7.88 ug/1 99 28) Azobenzen/ 1,2-Diphenylhyd 23.31 77 458897 6.83 ug/L # 85

(#) = qualifier out of range (m) = manual integration REFl.D GCMS0308.M Thu Mar 21 08:35:20 2002 Page 1

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