GCMS analysis report for sample AE01547, March 2002

NYC 9/11 Public Portal Document Library Search Compound Report

Data File : C: \MSDCHEM\1\5973N\02FEB21\01547.D Vial: 3 Acq On : 21 Feb 2002 4:52 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 21, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 4 1,3,5-Cycloheptatriene Concentration Rank 7

R.T. EstConc Area Relative to ISTD R.T.

4.38 0.05 ug/L 19011 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 1,3,5-Cycloheptatriene 92 C7H8 000544-25-2 7 2 1,3,5-Cycloheptatriene $$ Cycloh... 92 C7H8 000544-25-2 7 3 1,6-Heptadien-3-yne 92 C7H8 005150-80-1 5 4 1,6-Heptadien-3-yne 92 C7H8 005150-80-1 5 Abundance Scan 89 (4.379 min): 01547.D (-) m/z 91.00 100.00% 91

5000

44 51 i...... 4.00 anoeponosp) 4.20 4.40 4.60 4.80 84 0! ■' i “ ■ • l" ■ ■ i ■ ■ ■ • i “ ■ ■ i ■ • TTHI • । ■ • • > ।• i ■ ■ > • i • • • • i ■ ■ ■' i • ■ ■' i1 ■ • ■ i ’ ■11 ■ ■' ■ i'1 m/z 92.10 52.46% miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 93 95 100 Abundance #5571:1,3,5-Cycloheptatriene 91

5000 4.00 4.20 4.40 4.60 4.80 65 m/z 44.10 16.64% 27 01 " ।।■11 * i ■ —38,—46..7lsa., • ■ i “ ■ ‘ i ■ ■ ■ ■ i ■ ■ “ i ■ ■1' I 1110011111 d W miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #5570:1,3,5-Cycloheptatriene $$ Cyclohepta-1,3,5-triene $... 91 4.00 4.20 4.40 4.60 4.80 5000 m/z 51.00 15.57%

27 38 46— 51 61,| —mmmmmmp ■ ■ । 65 A A /I 01 —PTTT -mm । ■1 n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #5556: 1,6-Heptadien-3-yne Iir ■i ■ 1 1 ■ i r ITt T 91 4.00 4.20 4.40 4.60 4.80 m/z 83.90 3.43%

5000 65 WMWwAWMurooan 27 37 51 61. 86 , 0’ ■ ■ । । ■1 ■ ■ । ■ - “ i “ ■1111 ■ i ■ ■ 1 ■ i 1 ■ 1 ■ i ■ ■ ■ ■ i ' ■ 1 ■ i • n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 4.00 4.20 4.40 4.60 4.80

01547.D HP022102.M Mon Feb 25 10:55:24 2002 Page 6

NYC-WTC_000010075