DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02FEB27\02453.D Vial: 4 Acq On : 27 Feb 2002 5:47 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 27, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\l..-\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L ********************************************************************* Peak Number 5 1,3,5-Cycloheptatriene Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 4.37 0.03 ug/L 13322 1,4-Dichlorobenzene-d4 9.72

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,3,5-Cycloheptatriene 92 C7H8 000544-25-2 7 2 1,3,5-Cycloheptatriene $$ Cycloh... 92 C7H8 000544-25-2 7 3 1,6-Heptadien-3-yne 92 C7H8 005150-80-1 5 4 1,6-Heptadien-3-yne 92 C7H8 005150-80-1 5 Abundance Scan 88 (4.367 min): 02453. D (-) m/z 91.00 100.00% 91

5000

43 51 400 4.20 4.40 4.60 4.80 ol 1I1——un)BuI—UTT ‘I‘A‘‘I‘1+I1+4/‘I‘‘/1‘4*1I4I‘1111111 m/z 92.00 56.47% m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #5571:1,3,5-Cycloheptatriene 91

- 5000 400 4.20 4.40 4.60 4.80 65 m/z 51.00 15.45% 27 38 51

Abundance 46 Ol > ■ 11 ■ ■ ■ । ■ I ■ . ।।।, I ], ।. TT 20 25 30 35 40 45 ill..........1 > I ■ 11 ■1 > 111 ■ ■ > I ’ I' 11 50 55 60 65 70 75 80 85 90 #5570:1,3,5-Cycloheptatriene $$ Cyclohepta-1,3,5-triene $... 91 ■' i''1111 95 100 MMWWWo 4 00 4.20 4.40 4.60 4.80 5000 m/z 43.00 13.18%

65 27 38 46 51 61 । Ol TPTTTT TTTTT 111 ■ ■111 —I—PPT mfe-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #5557:1,6-Heptadien-3-yne 91 A,A/MA 400 4.20 4.40 4.60 4.80 m/z 49.00 3.14%

5000 65 w"yMAA 27 0 ..... 1..... %7 61' .111111, 1111' 11 " 11 111 " 86 ' i1" 111''11I1'' ,।11'1111 , 11 " ' I 1' i1 ''' i' m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 4.00 4.20 4.40 4.60 4.80

32453.D HP022102 .M Thu Feb 28 08:47:22 2002 Page 7

NYC-WTC_000005076