DEP GCMS data table, Jan-Feb 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02FEB27\02387.D Vial: 3 Acq On : 27 Feb 2002 4:57 pm Operator: Sample : 508 scan Inst : Instrumen Mise : February 27, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\l-..\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 4 1,3,5-Cycloheptatriene (CAS... Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 4.38 0.05 ug/L 21723 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,3,5-Cycloheptatriene (CAS) $$ ... 92 C7H8 000544-25-2 9 2 Tricyclo[4.1.0.0(2,7)]hept-3-ene... 92 C7H8 035618-58-7 7 3 METHYLFULVENE 92 C7H8 000000-00-0 7 4 1,3,5-Cycloheptatriene $$ Cycloh... 92 C7H8 000544-25-2 4 Abundance Scan 89 (4.378 min): 02387. D (-) m/z 91.10 100.00% 91

5000

> i ■ ‘ > i ■ ■ > ■ । । । l > ■ ■ ■ । i 43I 51 7 65I 86 4.00 4.20 4.40 4.60 4.80 Of 1' ।1 ■ ■ ■ ।■ m/z 92.00 60.80% mfe-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #5568:1,3,5-Cycloheptatriene (CAS) $$ Cycloheptatriene $$... 91 ...................................................... 5000 4.00 4.20 4.40 4.60 4.80 m/z 65.10 11.05% 39 _ 65 Of ' 11 ‘1 1' i ■'.1 61 , | 86 1' i '' ■ ■ i ■ ' 111 ■ '' 11 11' 11 ' '111 11' 1 I' 1 111 11' 1 I 1 1111 111 1 IT 1111 t1 m/z-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #5591: Tricyclo[4.1.0.0(2,7)]hept-3-ene (CAS) $$ Homobenzv... 91 .......... II..................... 4.00 4.20 4.40 4.60 4.80 5000 m/z 43.10 9.95%

65 0! 1 ' i ' 1 ■ ' i ' ' miz-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #5531: METHYLFULVENE A............ I A M_____________ 1 1 1 1 ‘ ' I ' 1 1 1 1 1 91 4.00 4.20 4.40 4.60 4.80 m/Z 51.00 4.72%

5000 WAA MAA)) 39 — . 65 0 " T" " I ' 1 1 I1 I " ■'45 61 , ।, I " " I " " I..... I i | I । । । . n. । ... I । I —IPPTTTT ,| 1 m/z-> 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 4.00 4.20 4.40 4.60 4.80

)2387.D HP022102.M Thu Feb 28 08:47:16 2002 Page 6

NYC-WTC_000005055