GCMS surrogate recovery results for sample AE03184, March 2002

NYC 9/11 Public Portal Document ulDrary bearen compound Report

Data File : C:\MSDCHEM\l\5973N\02MAR01\03184.D Vial : 4 Acq On : 1 Mar 2002 12:48 pm Operator: Sample : 508 scan Inst : Instrumen Mise : March 1, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library- : C:\DATABASE\WILEY7N. L ********************************************************************* Peak Number 5 2-Buten-l-ol, 3-methyl- (CA... Concentration Rank 6 R.T. EstConc Area Relative to ISTD R.T. 4.65 0.11 ug/L 38457 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Buten-l-ol, 3-methyl- (CAS) $$... 86 C5H10O 000556-82-1 47 2 2-Buten-l-ol, 3-methyl- (CAS) $$... 86 C5H10O 000556-82-1 37 3 2H-Pyran, tetrahydro- (CAS) $$ T... 86 C5H10O 000142-68-7 9 4 2H-Pyran, tetrahydro- $$ Oxacycl... 86 C5H10O 000142-68-7 9 Abundance Scan 113 (4.650 min): 03184. D (-) m/z 41.10 100.00% 41 71

88 57 5000- 44 53 85 1 1 N 4.40 4.60 4.80 5.00 0+ ■ i > ■ ■ ■ i ■ ■ ■ i ■ • ■ i । > < > ■ ■ '' l 49 1' i111' i' ■ ■ i' '' i111 ■ i'11 ■ i 111' ■' ■ i' ■ > i ■ ■ ■ ■ i'1 rn/z 71.00 96.95% n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #4075:2-Buten-1-ol, 3-methyl- (CAS) $$ Prenol $$ 2-METHYL... 71 41

5000- 53 86 —r),, . 4.40 4.60 4.80 5.00 67 m/z 88.00 59.80%

n/z-> 01 ■ ■ 11 ■ ■ ■ । ■ ■ ■ ■ ।

20 25 30 ■ I ■ ■ ■ 111

35 40 111' " 111 11'1 1 45 50 55 ■ i ■'1 ■ i ■

60 65 + HT —m 70 83 80 85 —m 75 ■ i ■ ■ ■ ■ । 90 95 ■

Abundance #4076: 2-Buten-1-ol, 3-methyl- (CAS) $$ Prenol $$ 2-METHYL... 71 41 4.40 4.60 4.80 5.00 5000 m/z 43.10 55.12% 53 86 27 68

Of • ■ i ■ ■ • > । ■ 1 ■ i''' ■ i ■' ■ i ■''' i'1 TT 111111111 I > ■ i " ■•i ■ ■ ■ ■ i 1111'111' miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #4171:2H-Pyran, tetrahydro- (CAS) $$ Tetrahydropyran $$ T... 41 4.40 4.60 4.80 5.00 m/z 57.00 53.45% 27 45 56 5000 85

30 53 67 0 111122/1/1 ■11 " '11 " I " ।1 ■ ■ । ‘ ■ 111111'11111 ■ ■ ■ j । 11**01]2001g—T m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 4.40 4.60 4.80 5.00

)3184.D HP022102.M Mon Mar 04 12:32:52 2002 Page 7

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