GCMS surrogate recovery results for sample AE03184, March 2002

NYC 9/11 Public Portal Document ulDLary searen compound Keporc

Data File : C:\MSDCHEM\1\5973N\02MAR01\03184.D Vial: 4 Acq On : 1 Mar 2002 12:48 pm Operator: Sample : 508 scan Inst : Instrumen Mise : March 1, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\MSDCHEM\1...\HP022102.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L ********************************************************************* Peak Number 4 4,4-DI-TRIDEUTEROMETHYL-2-A. .. Concentration Rank 10 R.T. EstConc Area Relative to ISTD R.T. 4.27 0.06 ug/L 21157 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 4,4-DI-TRIDEUTEROMETHYL-2-ALLYLC... 172 C11H12D6O 000000-00-09 2 Phosphoramidous difluoride $$ (D... 85 F2H2NP 025757-74-8 5 3 Phosphoramidous difluoride (CAS)... 85 F2H2NP 025757-74-8 5 4 1,2-Ethanediamine (CAS) $$ Ethyl... 60 C2H8N2 000107-15-3 4 Abundance Scan 79 (4.266 min): 03184. D (-) m/ z 85.00 100.00% 41 85

5000

49 60 .. A)... A, 4,00 4.20 4.40 4.60 ol ■ । ■ ■ ■ ■ । ■ 11 ■ ■ 1' i ■ i ■ ‘ ■ i 1 1 ■ ■ i 11 1 i ■ ■ ■ 11 m/z 41.10 83.93% m/z-> 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #68402: 4,4-DI-TRIDEUTEROMETHYL-2-ALLYLCYCLOHEXANONE 4 44

5000 4.00 4.20 4.40 4.60 47 m/z 43.00 47.23% 01 ----- n/z-> 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #3682: Phosphoramidous difluoride $$ (Difluorophosphino)am... 85 ksA , AA An AA A . 4.00 4.20 4.40 4.60 5000 m/z 42.10 27.07% 69 47

01 ■ ■ । ■ 11 31 11111111111111 "50I " " I " " I " " 66 I । " 11 ■ ‘ i 1 1 ■ ■ i n/z-> 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #3681: Phosphoramidous difluoride (CAS) $$ Aminodifluoroph... 85 4.00 4.20 4.40 4.60 m/z 60.10 26.90% 5000 69

31 46 50 66 0 ' ' i ■ ■ 1' i' 1' r i ■ ■1 ‘ i '1 1 111 ■ ■ 11 ‘ '1 1 i ■ 1 1' i' 1 ■ 11 । ■1 11 '1111'11 m/z—> 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 4.00 4.20 4.40 4.60

)3184.D HP022102.M Mon Mar 04 12:32:52 2002 Page 6

NYC-WTC_000006054