DEP GCMS reference results, Feb 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\FEB0 8 0 2\REFA.D Vial: 16 Acq On 8 Feb 2002 11:55 pm Operator: 209 GALOS Sample GC/MS SCAN 1/28 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 13 8:23 2002 Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Feb 08 15:29:22 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.35 152 321993 20.00 ug/1 0.00 10) Naphthalene-d8 15.99 136 1225159 20.00 ug/1 0.00 17) Acenaphthene-diO 21.31 164 663803 20.00 ug/1 0.00 29) Phenanthrene-diO 25.75 188 945766 20.00 ug/1 -0.01 38) Chrysene-dl2 33.83 240 621758 20.00 ug/1 -0.01 44) Perylene-dl2 38.11 264 396508 20.00 ug/1 -0.01

System Monitoring Compounds 37) 2,4-DDD 30.84 235 40680 3.46 ug/mL 0.34 Spiked Amount 5.000 Recovery = 69.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.97 74 23726 1.84 ug/1 100 3) bis(2-Chloroethyl)ether 11.73 93 57553 2.72 ug/1 99 4) 1,3-Dichlorobenzene 12.25 146 36965 1.47 ug/1 98 5) 1,4-Dichlorobenzene 12.40 146 40636 1.58 ug/1 98 6) 1,2-Dichlorobenzene 12.91 146 41335 1.69 ug/1 98 7) 2,2‘-oxybis(l-Chloropropan 13.23 45 91418 2.85 ug/1 99 8) N-Nitroso-di-n-propylamine 13.61 70 41983 2.77 ug/1 96 9) Hexachloroethane 13.76 117 9033 0.88 ug/1 95 11) Nitrobenzene 14.03 77 57370 2.28 ug/1 96 12) Isophorone 14.68 82 114616 2.69 ug/1 99 13) bis(2-Chloroethoxy)methane 15.36 93 68735 2.59 ug/1 97 14) 1,2,4-Trichlorobenzene 15.87 180 36161 1.72 ug/1 99 15) Naphthalene 16.05 128 151558 2.32 ug/1 99 16) Hexachlorobutadiene 16.59 225 8246 0.66 ug/1 96 18) Hexachlorocyclopentadiene 18.79 237 1783 N.D. 19) 2-Chloronaphthalene 19.56 162 89693 2.27 ug/1 99 20) Dimethylphthalate 20.64 163 131118 2.84 ug/1 99 21) 2,6-Dinitrotoluene 20.86 165 18607 1.78 ug/1 97 22) Acenaphthylene 20.83 152 133671 2.34 ug/1 99 23) Acenaphthene 21.40 153 100326 2.51 ug/1 100 24) 2,4-Dinitrotoluene 22.03 165 21472 1.62 ug/1 93 25) Diethylphthalate 22.78 149 132700 2.77 ug/1 99 26) 4-Chlorophenyl-phenylether 22.93 204 52951 2.57 ug/1 97 27) Fluorene 22.92 166 109484 2.51 ug/1 99 28) Azobenzen/ 1,2-Diphenylhyd 23.40 77 121529 2.41 ug/L 100

(#) = qualifier out of range (m) = manual integration REFA.D GCMS0208.M Wed Feb 13 08:27:33 2002 Page 1

NYC-WTC_000003829