GCMS reference analysis report, Feb 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\FEB 0802\REF.D Vial: 6 Acq On 8 Feb 2002 2:10 pm Operator: 209 GALOS Sample GC/MS SCAN 2/8 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Feb 11 12:02 2002 Quant Results File: GCMS0208.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Fri Feb 08 15:29:22 2002 Response via : Initial Calibration DataAcq Meth : GCMS0208

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) l,4-Dichlorobenzene-d4 12.35 152 320529 20.00 ug/1 0.00 10) Naphthalene-d8 15.99 136 1215332 20.00 ug/1 0.00 17) Acenaphthene-diO 21.30 164 650489 20.00 ug/1 0.00 29) Phenanthrene-diO 25.76 188 933005 20.00 ug/1 0.00 38) Chrysene-dl2 33.83 240 637333 20.00 ug/1 -0.02 44) Perylene-dl2 38.11 264 384314 20.00 ug/1 0.00

System Monitoring Compounds 37) 2,4-DDD 30.84 235 48358 4.17 ug/mL 0.34 Spiked Amount 5.000 Recovery = 83.40%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.97 74 25948 2.02 ug/1 97 3) bis(2-Chloroethyl)ether 11.74 93 61508 2.92 ug/1 99 4) 1,3-Dichlorobenzene 12.25 146 57322 2.29 ug/1 96 5) 1,4-Dichlorobenzene 12.39 146 60735 2.38 ug/1 96 6) 1,2-Dichlorobenzene 12.91 146 59090 2.43 ug/1 98 7) 2,21 -oxybis(1-Chloropropan 13.23 45 97568 3.06 ug/1 100 8) N-Nitroso-di-n-propylamine 13.61 70 43051 2.86 ug/1 94 9) Hexachloroethane 13.77 117 18286 1.79 ug/1 99 11) Nitrobenzene 14.03 77 61837 2.47 ug/1 98 12) Isophorone 14.69 82 117723 2.79 ug/1 100 13) bis(2-Chloroethoxy)methane 15.36 93 71848 2.73 ug/1 99 14) 1,2,4-Trichlorobenzene 15.88 180 51779 2.49 ug/1 97 15) Naphthalene 16.05 128 177125 2.74 ug/1 99 16) Hexachlorobutadiene 16.59 225 20522 1.65 ug/1 97 18) Hexachlorocyclopentadiene 18.79 237 3409 0.37 ug/1 95 19) 2-Chloronaphthalene 19.56 162 105627 2.72 ug/1 98 20) Dimethylphthalate 20.64 163 136471 3.02 ug/1 99 21) 2,6-Dinitrotoluene 20.86 165 21118 2.06 ug/1 99 22) Acenaphthylene 20.84 152 148111 2.64 ug/1 100 23) Acenaphthene 21.40 153 113563 2.90 ug/1 98 24) 2,4-Dinitrotoluene 22.03 165 24812 1.91 ug/1 91 25) Diethylphthalate 22.78 149 138629 2.95 ug/1 97 26) 4-Chlorophenyl-phenylether 22.94 204 58980 2.92 ug/1 97 27) Fluorene 22.92 166 120084 2.81 ug/1 98 28) Azobenzen/ 1,2-Diphenylhyd 23.41 77 131661 2.67 ug/L 99

(#) = qualifier out of range (m) = manual integration REF.D GCMS0208.M Mon Feb 11 12:05:38 2002 Page 1

NYC-WTC_000005156