DEP GCMS unknown compounds report, Mar 2002

NYC 9/11 Public Portal Document

Data File : C:\HPCHEM\1\DATA\FEB2502\1800.D Vial: 26 Acq On : 26 Feb 2002 2:33 pm Operator: Sample : gc/ms scan 1/25 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0208.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 1-Butanamine, 2-methyl- Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T.

8.19 0.30 ug/1 21539 1,4-Dichlorobenzene-d4 12.32

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1-Butanamine, 2-methyl- 87 C5H13N 000096-15-1 5 2 N-Ethyl formamide 73 C3H7NO 000627-45-2 5 3 1-Butanamine, 3-methyl- 87 C5H13N 000107-85-7 4 4 Formamfi.de, N,N-dimethyl- 73 C3H7NO 000068-12-2 4 Abundance f Scan 343 (8.193 min): 1800.D (-) m/ z 73.00 100.00% 73

L 5000 43 7.80 8.00 8.20 8.40 8.60

m/z-> 5 ................ 444.. TITTTTTT-HH +944 m/z 42.95 10 15 20 25 30 55 35 40 45 50 55 60 65 70 09,

75 80 85 90 95 29.28% Abundance #766: 1-Butanamine, 2-methyl- 30 ............................ /

5000 7.80 8.00 8.20 8.40 8.60 m/z 41.05.... 12.37% m/z-> —l TO—mTmmumu] "i"" i ""i" 15 41 44

5 10 15120 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 56 87

Abundance 30 73 7.80__ 8.00___ 8.20 8.40 8.60_ 5000 m/z 44.95 11.09% 44 58 27 15 41 '' " i' " ■ i ■ ■ " i' " 11'' " 11" ' i " '' i'1 " i' ■ ■111 " ' r " ' r 11' r ' " i " 1' i'1 " r " ' i11 ■ ■ i " ■' i' m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 Abundance #62884: 1-Butanamine, 3-methyl- 30 7.80 8.00 8.20 8.40 _ 8.60 m/z 71.00 8.28% 5000

27 41 44 55 59 70 73 87 " 1' I' ' i' " ' i' " 11'1 ■ l-rrn-rTHHHP TTTj-rTTTp-n-rpnnn-|n-^^ ' i ■11 ’ i " '111 m/z-> 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 7.80 8.00 8.20 8.40 8.60

1800.D GCMS0208.M Thu Feb 28 11:50:07 2002 Page 1

NYC-WTC_000003760