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GC/MS calibration data for TCLP method, Oct 2001

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Calibration table and chromatographic data for the TCLP method using GC/MS instrument 209, dated October 4, 2001.

NYC-WTC_000087659–000087669

Folder label: “GC/MS Scan 9/20/01

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\HPCHEM\1\DATA\OCT0201\22775.D Vial: 12 Acq On 3 Oct 2001 12:52 am Operator: 209 GALOS Sample gc/ms unknown Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 1,4-Dichlorobenzene-d4 Concentration Rank 1

R.T. EstConc Area Relative to ISTD R.T. 11.65 0.53 ug/1 64256 1,4-Dichlorobenzene-d4 11.79 Hit# Of 5 T^tative ID MW MolForm CAS# Qual 1 l,4-Dichlorefcenzene-d4 150 C6C12D4 003855-82-1 50 2 Benzene-1,/, 3,4-d4-, 5,6-dichloro- 150 C6C12D4 002199-69-1 45 3 2-Adamant/none 150 C10H14O 000700-58-3 25 4 Benzo [b]/hiophene-4-ol 150 C8H6OS 003610-02-4 9 <\bundance Scan 720 (11.647 min): 22775.D (-) m/z 149.90 100.00% 1!i0

5000 115

52 78 L TP /

c 11.40 11,60 11 ■80^12.00

•nfe-> 30 40 50 60 70 80 90 100 110 120 130 140 44^ 150 160 m/z 151.90 ( 68.21% Abundance #9593:1,4-Dichlorobenzene-d4 1!i0

553 115 T T T 78 11.40 11.60 11.80 12.00 52 m/z 115.00 . 36.28% 35 .................. ■n/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 Abundance #9592: Ben2ene-1.2,3,4-d4-, 5,6-dichloro- 150 .................... /....................

115 11.40 11.60 11.80 12.00 5000 52 78 m/z 77.95 18.86%

Tife-> 30 35 I 40 50 ' r ' ' ' r ' '' I' 60 70 80 7... 90 100 110 120 130 140 150 160 Abundance #9842: 2-Adamantanone 150 11.40 11.60 11.80 12.00 m/z 52.00 16.41% 79 553

54 72 93 104 117 1,1, , , , ,1.. ,1, , , 132 ■nZz-> 30 40 50 6b 70 8b 9b 100 110 120 130 140 150 160 11.40 11.60 11.80 12.00

22775.D NP091101.M Thu Oct 04 10:46:57 2001 Page 3

NYC-WTC_000087667

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