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GC/MS calibration data for TCLP method, Oct 2001

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Calibration table and chromatographic data for the TCLP method using GC/MS instrument 209, dated October 4, 2001.

NYC-WTC_000087659–000087669

Folder label: “GC/MS Scan 9/20/01

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\HPCHEM\1\DATA\OCT0201\22775.D Vial: 12 Acq On 3 Oct 2001 12:52 am Operator: 209 GALOS Sample gc/ms unknown Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Hexanone Concentration Rank 2 R.T. EstConc Area Relative to ISTD R.T. 6.47 0.52 ug/1 63374 1,4-Dichlorobenzene-d4 11.79 Hit# of Tentative ID MW MolFoirm CAS# Qual 1 2-Hexan(.qine 100 C6H12O 000591-78-6 86 2 Methyl/lsobutyl Ketone 100 C6H12O 000108-10-1 58 3 Propa/al 58 C3H6O 000123-38-6 43 4 2-Hexanone, 4-hydroxy-3-propyl- 158 C9H18O2 062338-17-4 40 Abundance Scan 156 (6.470 min): 22775.D (-) m/z 42.95 100700% 40

58 5000

71 85 100 6.20 6.40 6.60 6.80 ylTTTpTTp-rrrr^+TTTp-TTTpTTT^^TT-^^ m/z 58.05 57.00% n/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #1556:2-Hexanone 43

58 5000 -- r*-r 6.2o 6.40 6.^ 6.80 "mTz 41.05 13.30% 27 71 85 100 I ""I'I 'p"'r 7".I.......... |.n,....... T1/Z~> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #63354: Methyl Isobutyl Ketone 40

6,20 6,40 6.60 6.80 5000 m/z SYTOO 12.44% 58 85 100 67 TTpTTTlrTTTpTTpTTT-rf-^^ "" I"" I"" I"" I" I n/z-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #62333: Propanal 23 6.20 6.40 6.60 6.80 m/z 100^.05 10702%

5000 58

39 I " "I' I ' I" "I VAM.......... I" " I' "' I" " I"' ‘ r'" I" " I' ‘" I"'' I TTfe-> 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 6.20 6.40 6.60 6.80

22775.D NP091101.M Thu Oct 04 10:46:53 2001 Page 1

NYC-WTC_000087665

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NYC-WTC_000087665Source: NYC Law Department, mirrored locally

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