GC/MS calibration data for TCLP method, Oct 2001

NYC 9/11 Public Portal Document

. Quantitation Report (QT Reviewed) Data File : C:\HPCHEM\1\DATA\OCT1101\CAL10.D Vial: 2 Acq On : 11 Oct 2001 10:24 am Operator: 209 GALOS Sample : mix Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Oct 11 12:12 2001 Quant Results File: NP091101.RES Quant Method : C:\HPCHEM\1\METHODS\NP091101.M (RTE Integrator) Title : 209 625/TCLP calibration table 7/16/01 Last Update : Thu Sep 13 12:47:04 2001 Response via : Initial Calibration DataAcq Meth : NP091101

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-Dichlorobenzene-d4 11.77 152 417998 20.00 ug/1 -0.13 19) Naphthalene-d8 15.38 136 1636791 20.00 ug/1 -0.14 31) Acenaphthene-dlO 20.66 164 753344 20.00 ug/1 -0.15 49) Phenanthrene-dlO 25.08 188 1064291 20.00 ug/1 -0.15 59) Chrysene-dl2 33.13 240 673415 20.00 ug/1 -0.15 68) Perylene-dl2 37.23 264 450796 20.00 ug/1 -0.19

System Monitoring Compounds 4) 2-Fluorophenol 8.62 112 2121935 69.27 -^0.12 Spiked Amount 75.000 Recovery /92.36% 5) Phenol-d5 11.02 99 2568800 76.50 (ig/1 -0.12 Spiked Amount 75.000 Recovery 102.00% \ 6) 2-Chlorophenol-d4 11.28 132 2240558 70.94 ug/1 -0.13 \ Spiked Amount 75.000 Recovery 94.59% 7) 1,2-Dichlorobenzene-d4 12.29 152 975753 47.85/ug/1 -0.14 I Spiked Amount 50.000 Recovery = / 95.70% 20) Nitrobenzene-d5 13.40 82 1409860 ;50.90’ ug/1 -0.14 / Spiked Amount 50.000 Recovery = / 101.80% 32) 2-Fluorobiphenyl 18.67 172 2354608m 46.27 ug/1 -0.14 Spiked Amount 50.000 Recovery 92.54% 33) 2,4,6-Tribromophenol 23.09 330 442235 I66.75 ug/1 -0.14 Spiked Amount 75.000 Recovery 89.00% 62) Terphenyl-dl4 30.00 244 1916706 47.2 ug/1 -0. Spiked Amount 50.000 Recovery 94.44% Target Compounds (value 2) Pyridine 5.59 79 68284 2.02 ug/1 93 3) N-nitroso-dimethyl amine 5.48 74 209836 10.40 ug/1 100 8) Phenol • 11.05 94 413953 10.75 ug/1 100 9) bis(2-Chloroethyl)ether 11.19 93 316520 10.78 ug/1 99 10) 2-Chlorophenol 11.31 128 315813 10.61 ug/1 99 11) 1,3-Dichlorobenzene 11.67 146 333585 10.33 ug/1 100 12) 1,4-Dichlorobenzene 11.82 146 340373 10.46 ug/1 99 13) 1,2-Dichlorobenzene 12.32 146 312819 10.39 ug/1 98 14) 2-Methylphenol 12.63 108 277586 10.76 ug/1 99 15) 2,2'-oxybis(1-Chloropropan 12.65 45 438010 10.55 ug/1 # 86 16) 3&4-Methylphenol 13.04 108 285408 10.83 ug/1 99 17) N-Nitroso-di-n-propylamine 13.05 70 196709 10.64 ug/1 98 18) Hexachloroethane 13.16 117 116447 10.61 ug/1 96 21) Nitrobenzene 13.44 77 289890 10.70 ug/1 99 22) Isophorone 14.10 82 542218 10.45 ug/1 100 (#) = qualifier out of range (m) = manual integration CALIO.D NP091101.M Fri Oct 12 09:51:39 2001 Page 1

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