VOC analysis results, sample AE12738, June 4 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed) Data File C:\HPCHEM\l\DATA\02june04\0604C10.D Vial: 2 Acg On 4 Jun 2002 12:59 pm Operator: 201-wb Sample eal 10 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: GAS6.P Quant Time: Jun 4 13:37 2002 Quant Results File: HP052902.RES Quant Method : C:\HPCHEM\1\METHODS\HP052902.M (RTE Integrator) Title : VOCs BY EPA METHOD 524 Last Update : Fri May 31 14:34:13 2002 Response via : Initial Calibration DataAeq Meth : HP052902

Internal Standards R.T. Qlon Response Cone Units Dev(Min) 1) 1,4-DIFLUOROBENZ ENE 15.09 114 1360575 5.00 ug/L -0.02 24) CHLOROBENZENE-D5 ' 21.75 117 1278905 5.00 ug/L 0.00 52) 1,4-DICHLOROBENZENE-D4 26.93 152 632761 5.00 ug/L 0.00 System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.32 65 592687 4.82 ug/L -0.02 Spiked Amount 5.000 Recovery = 96.40% 3) ■ 4-BROMOFLUOROBENZENE 24.34 174 503778 4.65 ug/L 0.00 Spiked Amount 5.000 Recovery = 93.00% 25) TOLUENE-D8 18.45 98 1686958 5.23 ug/L -0.02 Spiked Amount 5.000 Recovery = 104.60% Target Compounds Qvalue 4) DICHLORODIFLUOROMETH7UJE 4.85 85 483603 9.96 ug/L 98 5) CHLOROMETHANE 5.35 50 674132 8.94 ug/L 97 6) VINYL CHLORIDE 5.59 62 453940 11.62 ug/L 98 7) BROMOMETHANE 6.56 94 248702 11.67 ug/L 99 8) CHLOROETHANE 6.71 64 376342 10.76 ug/L 98 9) TRICHLOROFLUOROMETHANE 7.27 101 725289 12.53 ug/L 98 10) Isopropyl Alcohol 7.87 45 240756 190.95 ug/L 93 11) l,l,2-Trichloro-l,2,2-trif 8.16 101 483694 10.90 ug/L 98 12) ACETONE 8.24 43 354778 24.99 ug/L 99 13) 1,1-DICHLOROETHENE 8.60 61 1049371 10.72 ug/L 97 14) METHYLENE CHLORIDE 9.61 49 918179 10.09 ug/L 94 15) METHYL TERT BUTYL ETHER 9.91 73 686308 9.76 ug/L 97 16) TRANS-1,2-DICHLOROETHENE 10.27 61 1067460 10.62 ug/L 93 17) 1,1-DICHLOROETHANE 11.16 63 1184489 10.52 ug/L 98 18) 2-BUTANONE (MEK) 11.99 43 368655 34.70 ug/L 96 19) 2,2-DICHLOROPROPANE 12.38 77 823317 9.80 ug/L 99 20) CIS-1,2-DICHLOROETHENE 12.47 96 678320 11.50 ug/L 92 21) CHLOROFORM 12.81 83 1284788 11.10 ug/L 99 2 2) BROMOCHLOROMETHANE 13.18 49 491132 9.89 ug/L 90 23) 1,2-DICHLOROETHANE 14.53 62 858555 10.64 ug/L 97 26) 1,1,1-TRICHLOROETHANE 13.69 97 986339 11.92 ug/L 97 27) 1,1-DICHLOROPROPENE 14.02 75 922000 11.81 ug/L 98 28) CARBON TETRACHLORIDE 14.29 117 846107 12.25 ug/L 100 29) BENZENE 14.63 78 2253920 11.78 ug/L 100 3 0) TRICHLOROETHENE 15.91 95 694026 12.11 ug/L 97 31) 1,2-DICHLOROPROPANE 16.25 63 562510 11.18 ug/L 95 32) DIBROMOMETHANE 16.93 174 280648 12.12 ug/L 88 3 3) BROMODICHLOROMETHANE 16.78 83 842938 11.70 ug/L 100 34) 2-CHLOROETHyL VINYL ETHER 17.26 63 160201 10.78 ug/L 92 35) METHYL ISO-BUTYL KETONE 17.34 58 323457 45.42 ug/L 97 36) CIS-1,3-DICHLOROPROPENE 17.87 75 755483 11.44 ug/L 99 37) TOLUENE 18.62 91 2411221 12.07 ug/L 97 38) TRANS-1,3-DICHLOROPROPENE 18.91 75 536558 11.34 ug/L 98 39) 1,1,2-TRICHLOROETHANE 19.28 97 347978 11.84 ug/L . 98 40) TETRACHLOROETHENE 20.07 166 686304 12.45 ug/L 96 41) 1,3-DICHLOROPROPANE 19.81 76 648916 11.27 ug/L 99 42) DIBROMOCHLOROMETHANE 20.51 129 443907 12.40 ug/L 99 43) 1,2-DIBROMOETHANE 20.95 107 338682 11.62 ug/L 96 44) CHLOROBENZENE 21.84 112 1554083 12.29 ug/L 95 45) 1,1,1,2-TETRACHLOROETHANE 21.89 131 525398 12.46 ug/L 98 46) 2-HEXANONE 19.18 43 590572 42.53 ug/L 99 (#) = qualifier out of range (m) = manual integration 0604C10.D HP052902.M Tue Jun 04 13:37:58 2002 Page 1

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