Volatile organic compound analysis results, sample AE08016, April 2002

NYC 9/11 Public Portal Document Quantitation Report (Not Reviewed)

Data File C:\HPCHEM\l\DATA\02apr05\0405R5.D Vial: 3 Acq On 5 Apr 2002 1:30 pm Operator: 201-wb Sample ref 5 Inst : GC/MS Ins Mise Multiplr: 1.00 MS Integration Params: RTEINT.P Quant Time: Apr 5 14:08 2002 Quant Results File: HP031802.RES

Quant Method C:\HPCHEM\1\METHODS\HP031802.M (RTE Integrator) Title VOCs BY EPA METHOD 524 Last Update Thu Apr 04 11:11:24 2002 Response via Initial Calibration DataAcq Meth HP031802

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-DIFLUOROBENZENE 15.05 114 1384996 5.00 ug/L 0.00 24) CHLOROBENZENE-D5 21.71 117 1241147 5.00 ug/L 0.00 52) 1,4-DICHLOROBENZENE-D4 26.88 152 626276 5.00 ug/L 0.00

System Monitoring Compounds 2) 1,2-DICHLOROETHANE-D4 14.29 65 629127 5.51 ug/L 0.00 Spiked Amount 5.000 Recovery = 110.20% 3) 4-BROMOFLUOROBENZENE 24.30 174 533313 4.76 ug/L 0.00 Spiked Amount 5.000 Recovery = 95.20% 25) TOLUENE-D8 18.41 98 1579853 5.26 ug/L 0.00 Spiked Amount 5.000 Recovery = 105.20%

Target Compounds Qvalue 4) DICHLORODIFLUOROMETHANE 4.83 85 183482 4.01 ug/L 97 5) CHLOROMETHANE 5.42 50 218866 4.00 ug/L 97 6) VINYL CHLORIDE 5.57 62 238014 6.80 ug/L 97 7) BROMOMETHANE 6.55 94 169882 5.17 ug/L 95 8) CHLOROETHANE 6.68 64 196534 5.79 ug/L 95 9) TRICHLOROFLUOROMETHANE 7.23 101 415464 6.02 ug/L 99 12) ACETONE 8.21 43 71392 7.62 ug/L 100 13) 1,1-DICHLOROETHENE 8.55 61 369260 4.46 ug/L 93 14) METHYLENE CHLORIDE 9.55 49 322410 4.38 ug/L 97 15) METHYL TERT BUTYL ETHER 9.86 73 321059 4.32 ug/L 98 16) TRANS-1,2-DICHLOROETHENE 10.22 61 363608 4.38 ug/L 96 17) 1,1-DICHLOROETHANE 11.10 63 393873 4.14 ug/L 97 18) 2-BUTANONE (MEK) 11.95 43 45221 4.44 ug/L 98 19) 2,2-DICHLOROPROP7U^E 12.33 77 328620 4.38 ug/L 95 20) CIS-1,2-DICHLOROETHENE 12.43 96 226559 4.05 ug/L 97 21) CHLOROFORM 12.75 83 446712 4.34 ug/L 96 22) BROMOCHLOROMETHANE 13.13 49 170628 3.99 ug/L 88 23) 1,2-DICHLOROETHANE 14.47 62 322250 4.53 ug/L 99 26) 1,1,1-TRICHLOROETHANE 13.66 97 351770 5.02 ug/L 96 27) 1,1-DICHLOROPROPENE 13.98 75 309850 4.81 ug/L 97 28) CARBON TETRACHLORIDE 14.23 117 315681 5.23 ug/L 98 29) BENZENE 14.57 78 744676 4.64 ug/L 97 30) TRICHLOROETHENE 15.85 95' 241229 4.81 ug/L 95 31) 1,2-DICHLOROPROPANE 16.21 63 182248 4.35 ug/L 96 32) DIBROMOMETHANE 16.87 174 111971 4.71 ug/L 96 33) BROMODICHLOROMETHANE 16.72 83 313861 4.94 ug/L 99 34) 2-CHLOROETHYL VINYL ETHER 17.21 63 59114 3.53 ug/L 99 35) METHYL ISO-BUTYL KETONE 17.30 58 26511 3.70 ug/L 99 36) CIS-1,3-DICHLOROPROPENE 17.83 75 265836 4.37 ug/L 98 37) TOLUENE 18.58 91 792858 4.61 ug/L 99 38) TRANS-1,3-DICHLOROPROPENE 18.87 75 209393 4.67 ug/L 97 39) 1,1,2-TRICHLOROETHANE 19.24 97 124999 4.40 ug/L 96 40) TETRACHLOROETHENE 20.02 166 244565 4.80 ug/L 98 41) 1,3-DICHLOROPROPANE 19.77 76 229551 4.39 ug/L 99 42) DIBROMOCHLOROMETHANE 20.47 129 174445 4.76 ug/L 94 43) 1,-2-DIBROMOETHANE 20.91 107 125585 ■4.34 ug/L 96 44) CHLOROBENZENE 21.79 112 514801 4.44 ug/L 94 45) 1,1,1,2-TETRACHLOROETHANE 21.84 131 194754 4.76 ug/L . 96 46) 2-HEXANONE 19.14 43 59480 4.49 ug/L 97 47) ETHYLBENZENE 21.83 91 963992 4.82 ug/L 99 48) P & M-XYLENE 22.00 106 624001 9.15 ug/L 89

(#) = qualifier out of range (m) = manual integration 0405R5.D HP031802.M Fri Apr 05 14:09:06 2002 Page 1

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