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GCMS analysis results for sample AD24640, Nov 2001

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Laboratory report documenting GCMS analysis of sample AD24640 with detection of unknown compounds on November 13, 2001.

NYC-WTC_000068659–000068671

Folder label: “508 Scan X 10/16/01 A 11/5/01

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NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\HPCHEM\1\DATA\NOV0501\24640.D Vial: 13 Acq On : 5 Nov 2001 11:40 pm Operator: 209 GALOS Sample : gc/ms unknown Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\NP103001.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 3 2-Pentanone, 4-hydroxy-4-methy Concentration Rank 1 R.T. EstConc Area Relative to ISTD R.T. 7.70 0.99 ug/1 159698 1,4-Dichlorobenzene-d4 11.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Pentanone -hydroxy-4-methyl- 116 C6H12O2 000123-42-2 56 2 3-Hydro: -pentanone 102 C5H10O2 003142-66-3 32 3 Morphi ne, 4-methyl- 101 C5H11NO 000109-02-4 9 4 5-Hl :en-2-one 98 C6H10O 000109-49-9 7 Abundance Scan 289 (7.695 min); 24640.D (-) m/z 42.95 100.00% 4(3

JV.. 5000 59

101 7.40 7.60 7.80 8.00

10 20 30 38 I 40 5o' 53 H60i.......... 70 ........... 80 90 .....110 m/z 100 59.05 49.94% Abundance #64274: 2-Pentanone, 4-hydroxy-4-methyl- 4(3

5000 59 7.40 7.60 7.80 8.00 m/z 101.05 23.89% 27 101 83 m/z-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #1691:3-Hydroxy-2-pentanone 31 59

7.40 7.60 7.80 8.00 5000 m/z 58.05 15.52% 45 15 I TTfe-> 10 20 30 40 50 60 70 80 90 100 110 Abundance #1640: Morpholine, 4-methyl- _ 4(3 _7:4O_Z6O__A8O_8W__ m7z 41.05 9.59%

5000

101 15 71 27 I ' ' ' ' I ’ ’ I ' ' ' ' I I ' ' ' ' I ' ' ' ' I ' ' ' ' I ■nfe-> 10 20 30 40 50 60 70 80 90 100 110 7.40 7.60 7.80 8.00

24640.D NP103001.M Fri Nov 09 12:25:42 2001 Page 3

NYC-WTC_000068669

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NYC-WTC_000068669Source: NYC Law Department, mirrored locally

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