GCMS calibration verification data for sample AE06981, April 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\l\DATA\APR1802\C;^20. Vial: 2 Acq On 18 Apr 2002 12:30 pm /( ? Operator: Sample Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 19 8:15 2002 Quant Results File: GCMS0412.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed Apr 17 11:48:30 2002 Response via : Initial Calibration DataAcq Meth : GCMS0412

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.21 152 634921 20.00 ug/1 -0.03 10) Naphthalene-d8 15.85 136 2306456 20.00 ug/1 -0.03 17) Acenaphthene-dlO 21.15 164 1317834 20.00 ug/1 -0.02 30) Phenanthrene-dlO 25.60 188 1965240 20.00 ug/1 -0.02 39) Chrysene-dl2 33.65 240 1219392 20.00 ug/1 -0.03 45) Perylene-dl2 37.87 264 762289 20.00 ug/1 -0.05

System Monitoring Compounds 28) TCMX 0.00 209 0 0.00 ug/L Spiked Amount 10.000 Recovery = 0.00% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.85 74 251075 18.17 ug/1 97 3) bis(2-Chloroethyl)ether 11.63 93 395995 18.41 ug/1 99 4) 1,3-Dichlorobenzene 12.11 146 442755 19.96 ug/1 98 5) 1,4-Dichlorobenzene 12.26 146 457670 20.51 ug/1 98 6) 1,2-Dichlorobenzene 12.78 146 422165 20.37 ug/1 98 7) 2,2'-oxybis(1-Chloropropan 13.09 45 519883 17.50 ug/1 98 8) N-Nitroso-di-n-propylamine . 13.49 70 254804 18.06 ug/1 99 9) Hexachloroethane 13.63 117 158043 19.33 ug/1 91 11) Nitrobenzene 13.90 77 393637 19.47 ug/1 . 98 12) Isophorone 14.54 82 716976 18.74 ug/1 99 13) bis (2-Chloroethoxy)methane 15.22 93 478620 19.20 ug/1 99 14) 1,2,4-Trichlorobenzene 15 .'74 180 381562 21.76 ug/1 99 15) Naphthalene 15.90 128 1143548 20.62 ug/1 99 16) Hexachlorobutadiene 16.44 225 197150 22.48 ug/1 99 18) Hexachlorocyclopentadiene 18.64 237 115215 19.77 ug/1 99 19) 2-Chloronaphthalene 19.41 162 712527 20.50 ug/1 98 20) Dimethylphthalate 20.50 163 810044 20.22 ug/1 99 21) 2,6-Dinitrotoluene 20.71 165 189470 19.78 ug/1 98 22) Acenaphthylene 20.68 152 985983 20.28 ug/1 100 23) Acenaphthene 21.25 153 703961 20.37 ug/1 99 24) 2,4-Dinitrotoluene 21.88 165 232557 18.44 ug/1 97 25) Diethylphthalate 22.64 149 757320 19.71 ug/1 99 26) 4-Chlorophenyl-phenylether -22.78 204 376058 22.05 ug/1 99 27) Fluorene 22.76 166 778930 21.28 ug/1 98 29) Azobenzen/ 1,2-Diphenylhyd 23.25 77 734036 18.05 ug/L 98 31) N-Nitrosodiphenylamine 23.18 168 336482 20.58 ug/1 98 32) 4-Bromophenyl-phenylether 24.25 248 208568 21.86 ug/1 96

(#) = qualifier out of range (m) = manual integration CAL20.D GCMS0412.M Fri Apr 19 08:24:45 2002 Page 1

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