GC/MS calibration results for Method 508, April 9 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\l\DATA\020409\0318REFl.D Vial: 4 Acq On 9 Apr 2002 5:58 pm Operator: McLean Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Apr 26 13:40:45 2002 Quant Results File: SCANAPR0902.R

Quant Method : C:\MSDCHEM\1...\SCANAPR0902.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Last Update : Fri Apr 26 13:24:19 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN1

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 10.66 152 2548120 40.00 ug/1 0.00 10) Naphthalene-d8 15.77 136 9650886 40.00 ug/1 -0.01 17) Acenaphthene-dlO 23.66 164 5491400 40.00 ug/1 0.00 30) Phenanthrene-dlO 30.89 188 8731180 40.00 ug/1 0.00 38) Chrysene-dl2 39.10 240 7022254 40.00 ug/1 -0.02 44) Perylene-dl2 42.30 264 3671872 40.00 ug/1 0.00

System Monitoring Compounds 2 7) TCMX 0.00 207 Od 0.00 ug/1 Spiked Amount 4.000 Recovery 0.00% 37) 2,4-DDD 36.62 235 525752 4.79 ug/ml 0.00 Spiked Amount AXT^O Recovery =

Target Compounds 6/^ Qvalue 2) N-nitrosodimethylamine 3.66 74 425178m 12.46 ug/1 3) bis(2-Chloroethyl)ether 9.94 93 1386150 18.27 ug/1 99 4) 1.3-Dichlorbenzene 10.41 146 965231 10.51 ug/1 99 5) 1,4-Dichlorobenzene 10.72 146 1033549 11.16 ug/1 98 6) 1,2-Dichlorobenzene 11.23 146 1076619 12.34 ug/1 97 7) 2,2'oxybis(1-Chloropropane 12.04 45 1280927 9.98 ug/1 99 8) N-Nitroso-di-n-propylamine 12.51 43 960441 18.82 ug/1 99 9) Hexachloroethane 12.52 119 234783 7.53 ug/1 97 11) Nitrobenzene 12.92 77 1326032 16.19 ug/1 98 12) Isophorone 14.03 82 2637103 18.96 ug/1 99 13) bis(2-Chloroethoxy) methan 15.25 93 1728955 19.32 ug/1 100 14) 1,2,4-Trichlorobenzene 15.61 180 920705 13,17 ug/1 99 15) Naphthalene 15.85 128 4030886 17.34 ug/1 99 16) Hexachlorobutadiene 16.62 225 279196 7.31 ug/1 98 18) 2-Chloronaphthalene 21.13 162 2378322 15.79 ug/1 99 19) Acenaphthylene 22.95 152 3685093 17.51 ug/1 100 20) Dimethyl phthalate 23.04 163 3124168 19.01 ug/1 99 21) 2,6-Dinitrotoluene 23.15 77 153096 17.41 ug/1 # 80 .22) Acenaphthene 23.79 153 2727150 17.58 ug/1 100 23) 2,4-Dinitrotoluene 24.92 165 509009 12.82 ug/1 99 24) Fluorene 26.20 166 3057898 17.96 ug/1 100 25) Diethyl phthalate 26.41 149 3119916 19.47 ug/1 99 26) 4-Chlorophenyl-phenylether 26.53 204 1371104 17.17 ug/1 96 28) N-Nitrosodiphenylamine 27.13 168 1052762 16.36 ug/1 98 29) Azobenzene 27.21 77 3261504 17.18 ug/1 99 31) Hexachlorobenzene 28,77 284 940069 16.40 ug/1 100 32) 4-Bromophenyl-phenylether 28.89 248 818371 17.42 ug/1 97 33) Phenanthrene 30.99 178 4553301 18.63 ug/1 100

(#) = qualifier out of range (m) = manual integration 0318REF1.D SCANAPR0902.M Fri Apr 26 13:47:50 2002 Page 1

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