GC/MS calibration results for Method 508, April 9 2002

NYC 9/11 Public Portal Document

Quantitation Report (QT Reviewed)

Data File C:\MSDCHEM\l\DATA\020409\CAL4.D Vial: 2 Acq On 9 Apr 2002 4:06 pm Operator: McLean Sample Inst Instrutnen Mise Multiplr: 1.00 MS Integration Params: EVENTS.E Quant Time: Apr 26 11:22:16 2002 Quant Results File: SCANAPR0902.R

Quant Method : C:\MSDCHEM\1...\SCANAPR0902 .M (Chemstation Integrator) Title : Method 508 GC/MS Scan Last Update : Mon Apr 15 14:13:03 2002 Response via : Initial Calibration DataAcq Meth : 508SCAN1

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 10.67 152 2785356 40.00 ug/1 0.00 10) Naphthalene-d8 15.78 136 10796668 40.00 ug/1 0.00 17) Acenaphthene-dlO 23.67 164 5641738 40.00 ug/1 0.00 31) Phenanthrene-dlO 30.90 188 9129082 40.00 ug/1 0.00 39) Chrysene~dl2 39.12 240 7832699 40.00 ug/1 0.00 45) Perylene-dl2 42.31 264 4093202 40.00 ug/1 0.00

System Monitoring Compounds 2 8) TCMX 0.00 207 Od 0.00 ug/1 Spiked Amount 4.000 Recovery = 0.00% 38) 2,4-DDD 0.00 235 Od 0.00 ug/ml Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitrosodimethylamine 3.56 74 3576390 80.04 ug/1 100 3) bis(2-Chloroethyl)ether 9.97 93 6615707 79.76 ug/1 100 4) 1.3-Dichlorbenzene 10.42 146 8132911 81.04 ug/1 99 5) 1,4-Dichlorobenzene 10.74 146 8216540 81.16 ug/1 100 6) 1,2-Dichlorobenzene 11.26 146 7672037 46^i]g/1 100 7) 2,2'oxybis(1-Chloropropane 12.05 45 5417799 J8.63>Ug/l 100 8) N-Nitroso-di-n-propylamine 12.56 43 4339647 77.78 ug/1 99 9) Hexachloroethane 12.53 119 2738980 80.34 ug/1 99 11) Nitrobenzene 12.97 77 7273803 79.39 ug/1 99 12) Isophorone 14.06 82 12533968 80.54 ug/1 99 13) bis(2-Chloroethoxy) methan 15.29 93 7983119 79.74 ug/1 99 14) 1,2,4-Trichlorobenzene 15.64 180 6450502 82.45 ug/1 100 15) Naphthalene 15.88 128 20872059 80.27 ug/1 100 16) Hexachlorobutadiene 16.63 225 3557550 83.29 ug/1 99 18) Hexachlorocyclopentadiene 19.80 237 2219365 89.43 ug/1 99 19) 2-Chloronaphthalene 21.17 162 12576671 81.29 ug/1 99 20) Acenaphthylene 22.98 152 18169338 84.02 ug/1 99 21) Dimethyl phthalate 23.09 163 13778930 81.59 ug/1 99 22) 2,6-Dinitrotoluene 23.21 77 819546 90.70 ug/1 96 23) Acenaphthene 23.83 153 12919371 81.05 ug/1 99 24) 2,4-Dinitrotoluene 24.97. 165 3417587 83.76 ug/1 98 25) Fluorene 26.23 166 14517907 82.98 ug/1 100 26). Diethyl phthalate 26.46 149 13436371 81.61 ug/1 99 27) 4-Chlorophenyl-phenylether 26.55 204 6775657 82.61 ug/1 99 29) N-Nitrosodiphenylamine 27.18 168 5526877 83.58 ug/1 99 30) Azobenzene 27.26 77 16187011 83.00 ug/1 99 32) Hexachlorobenzene 28.82 284 5027966 83.87 ug/1 98 33) 4-Bromophenyl-phenylether 28.91 248 4155011 84.60 ug/1 98

(#) = qualifier out of range (m) = manual integration CAL4 '.D SCANAPR0902 .M Fri Apr 26 11:29:32 2002 Page 1

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