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GCMS unknown compound analysis, sample AE05697, April 2002

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Laboratory record of gas chromatography mass spectrometry analysis for unknown compounds and surrogates on April 9, 2002.

NYC-WTC_000059267–000059276

Folder label: “GCMS X 3/11/02 A 4/1/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\APRO1O2\5697.D Vial: 12 i' Acq On : 1 Apr. 2002 11:09 pm Operator: Sample : gc/ms scan 3/11 Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0308.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************** Peak Number 2 1,6-Dioxacyclododecane-7,12-di Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

21.07 0.24 ug/1 52580 Acenaphthene-dl0 21.19

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,6-Dioxacyclo<^decane-7,12-dione 200 C10H16O4 000777-95-7 32^ 2 Hexanedioic acid, monoethyl ester 174 C8H14O4 000626-86-8 22 3 Pentanedioic acid, ethyl methyl est 174 C8H14O4 051503-30-1 16 A..A'-? ' ' 5-Tetrahydropyridazine 84 C4H8N2 000694-06-4 II Abundance Scan 1746 (21.074 min): 5697.D (-) m/z 5 5." 0 0 10 0.00% . 55 i I i 5000 84 111 41 129

AJL ^1 I m/z->.__20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 -190 200 141 I*'-.......... I m/z 20.80 21.00 21.20 21.40 84.00 52.65% Abundance #22852: 1,6-Dioxacyclododecane-7,12-dione 515

5000 27 84 42 20.80 21.00 21.20 21.40 100 71 129 m/z 111.00 33.85% JI ■ ■. 11.1.11.... I, i..... I, n+TT 200 172 n/z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 ^kbundance #16125: Hexanedioic acid, monoelhyl ester 55 111 129 i I 88 20.80 21.00 21,20 21.40 101 m/z 56.00 29.22% 5000 45 I I 157 J m/z-> :20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #16127: Pentanedioic acid, ethyi methyl ester I 2i9 59 ■ 20.80 21.00 21.20 21.40 129 m/z 129.10 26.47% 42 5000 101 74 .87 114 143 .... .... i|........... ........... ......... ..... .... Hr I . ...... 'tj........ )n/2--> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 20.80 21.00 21.20 21.40

5697.D GCMS0403.M Thu Apr 04 13:58:02 2002 Page 2

NYC-WTC_000059275

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NYC-WTC_000059275Source: NYC Law Department, mirrored locally

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