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GCMS analysis results, sample AE00738, January 2002

Machine-extracted title · confidence 85%

Gas chromatography-mass spectrometry analysis of sample AE00738 conducted on 1/29/02, detecting unknown compounds and 2,4-DDD surrogate at 99 ug with 5.0 MDL.

NYC-WTC_000051948–000051966

Folder label: “GCMS X 1/10/02 A 1/16/02

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NYC 9/11 Public Portal Document

Data File : C:\MSDCHEM\1\5973N\02JAN16\00738.D Vial: 6 - Acq On : 16 Jan 2002 7:17 pm Operator: Sample : 508scan Inst : Instrumen Mise : January 16, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L ********************************************************************* Peak Number 4 2-Propanol, 1-butoxy- (CAS)... Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T.

8.23 0.28 ug/L 97433 1,4-Dichlorobenzene-d4 9.71

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Propanol, 1-butoxy- (CAS) $$ 1... 132 C7H16O2 005131-66-8 45 2 Pinacolyl alcohol 102 C6H140 000464-07-3 39 3 Ethanol, 2-butoxy- (CAS) $$ 2-Bu... 118 C6H14O2 000111-76-2 38 4 2-Butanol, 3,3-dimethyl- (CAS) $... 102 C6H140 000464-07-3 36 Abundance Scan 425 (8.226 min): 00738.D (-) m/z 57.10 100.00% 45 57

5000 87

39 ATP —7.80 8.00 8.20 8.40 8.60 51 0 ■ ■ l ■ ■' ■ l • •'11 ■ -H mpm 111 11" " i m/ z 45.10 98.53% m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #28054: 2-Propanol, 1 -butoxy- (CAS) $$ 1-N-BUTOXY-2-PROPAN... 45 57

5000 1 1 ' 1 1 1 1 1 7.80 8.00 8.20 8.40 8.60 31 87 m/ z 87.10 42.43% 75 -HT 01 " i " " i ’ T ■ • • 11 > ■11 ■ > .. TIT i " '11" " i TT m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #9685: Pinacolyl alcohol 45 57 7.80 8.00 8.20 Ammm 8.40 8.60 5000 m/z 41.10 40.25% 69 87

33 , 102 Of " I " " I H " I'11 ’ I' "' I " '' —Tp I" "I... . nF 1' i" ■11" " r 1" r ■'11' n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #17833: Ethanol, 2-butoxy- (CAS) $$ 2-Butoxyethanol $$ 2-n... A../. . 57 7.80 8.00 8.20 8.40 8.60 m/z 56.10 37.27% 5000 45 87

Of -TTP+ ,63.. ...... 100 hamhmmmommn " I" " I''" I ■'" I ’ ■'11 ■ m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 7.80 8.00 8.20 8.40 8.60

)0738.D SCAN508.M Thu Jan 17 08:17:46 2002 Page 6

NYC-WTC_000051957

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NYC-WTC_000051957Source: NYC Law Department, mirrored locally

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