GCMS results for sample AE00463, Jan 24 2002

NYC 9/11 Public Portal Document

Llbrary search Compound Report

Data File : C:\MSDCHEM\1\5973N\02JAN11\00463.D Vial: 5 Acq On : 11 Jan 2002 5:25 pm Operator: Sample : 508 scan Inst : Instrumen Mise : January 11, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L

Peak Number 1 2-Butyne-1,4-diol, diformat... Concentration Rank 7 R.T. EstConc Area Relative to ISTD R.T. 4.85 0.14 ug/L 44770 1,4-Dichlorobenzene-d4 9.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Butyne-1,4-diol, diformate $$ ... 142 C6H6O4 036677-73-3 9 2 Cyclobut-l-enylmethanol 84 C5H80 000000-00-0 9 3 1-Hexene, 6-bromo- 162 C6HllBr 002695-47-8 9 4 4-Pentenal (CAS) $$ 4-Pentenal-84 C5H8O 002100-17-6 9 Abundance Scan 129 (4.847 min): 00463.D (-) m/ z 84.00 100.00% 59 84 41 5000 51 i ■ ’ ' 1 i ■ ■ 4.40 4.60 4.80 5.00 5.20 01.............. . ■ ■ । ■ ■ ■ । ■ ■ ■ ■ । ■1 ■ ■ i ■ I " " I " " FTT’i " " | i 1 ■1 ■ i m/z 59.10 80.00% m/z—> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #37451: 2-Butyne-1,4-diol, diformate $$ 2-Butynylene formate 23 39

51 A - 5000 4.40 4.60 4.80 5.00' 5.20 68 m/z 55.10 75.81% 01' 111 <‘| nor 86 96 /z-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #3313: Cyclobut-1-enylmethanol 5)5 . ........... . 83 4.40 4.60 4.80 5.00' 5.20 27 39 5000 m/ z 83.00 68.45%

I 1 66

n/z-> 0 । 11 ।' i1' NIT 20 30 40 Ll..... 50 60 70 80 90 100 110 120 130 140 150 160 170 Abundance #61496:1-Hexene, 6-bromo- 41 55 4.40 4.60 4.80 5.00 5.20 m/z 41.10 65.86% 83 5000 27 67

m/z-> 0 ■ ■ i1 ■" । ■1 ■ 11 20 30 40 • ■ I ■ 50 60 70 80 '' ■ ।r 1 ■ ■ i'' ■ ■ i' ■ ■111' ■ ■ ।

90 100 110 120 130 140 150 160 170 136 162 111 1 I 1 1 1 rT >r'। l f ■ ■ । i —4 4 40 4.60 4.80 5.00 5.20

00463.D SCAN508.M Mon Jan 14 10:46:56 2002 Page 3

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