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GCMS analysis results for sample AE00466, Jan 18 2002

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Laboratory report documenting gas chromatography-mass spectrometry analysis of environmental sample AE00466 conducted on January 18, 2002.

NYC-WTC_000051263–000051282

Folder label: “GCMS X 1/8/02 A 1/10/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\1\5973N\02JAN10\00473.D vial: 8 Acq On 10 Jan 2002 8:36 pm Operator: Sample : 508 scan ext 1/8 Inst : Instrumen Mise : January 10, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N. L ********************************************************************* Peak Number 13 .beta.-methyl ionone Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

36.56 1.40 ug/L 729478 Perylene-dl2 34.42

Hit# of 5 Tentative ID MW MolForm CAS# Qual -------------------------- O 1 .beta.-methyl ionone 206 C14H22O 000000-00-0 43 . 2 4a,4b,8,8,2-pentamethyl-1-butylp... 318 C23H42 091548-79-7 42 091548-78-6 42 wir(o* 60 3 trans-4a,4b,8,8,2-pentamethyl-1-... 318 C23H42 4 1,3,4,7,7-PENTAMETHYL-2-OXA-BICY... 206 C14H22O 000000-00-0 38 Abundance Scan 2907 (36.563 min): 00473.D (-) m/z 191.15 100.00% 191

5000 95 69 123 , 163 ' i 1 1 1 1 I 1 1 1 1 I ' ' ■ ■ i ■ ' 1 ■ i ■

m/z-> 0 LI H — + 44. **mPP 41 218 245 40 60 80 100 120140160180 200 220 240 260280 300 320 340 360 380 400 412 rrrh i ■ 36.20 36.40 36.60 36.80 m/z 95.10 48.01% Abundance #124627: .beta.-methyl ionone 191

5000 57 TT T IT

107 149 0-TTTTTEOTETICTUTTTTTTTTT TTTTTTTTTT‘T11 73 I''" 11' " I r1" i" " I" " i' m/z~> 40 60 80 100120140160180 200 220 240 260 280 300 320 340 360 380 400 Abundance #270029: 4a,4b,8,8,2-pentamethyl-1 -butylperhydrophenanthrene 191

69 36.20 3640 36.60 36.80........ 5000 95 m/ z 69.10 29.08% 123 303 165 .............................................. 0- TTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTTT m/z-> 40 60 80 100120140 160180 200 220 240 260 280 300 320 340 360 380 400 Abundance #270028: trans-4a,4b,8,8,2-pentamethyl-1 -butylperhydrophen... 191 36.20 36.40 36.60 36.80 m/z 123.10 27.31% 69 95 5000 123 Wr) wW t 303 _____ 0 T‘‘1 ‘ __ I_____ 165 II_____ I I —OIUBUTT—u— 10111111101011"0"IUUIUT0C0 _______________________ 1.................. I—B03T3TTTITET 111"1111" i" " i'1" i" " i" " i' m/z-> 40 60 80 100 120 140160180 200 220 240 260 280 300 320 340 360 380 400 3620 36.40 36.60 36.80 '

00473 .D SCAN508 .M Fri Jan 11 10:09:10 2002 Page 15

NYC-WTC_000051281

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