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GCMS analysis results for sample AD31631, Jan 28 2002

Machine-extracted title · confidence 100%

Laboratory report showing GCMS analysis of sample AD31631 including unknown compounds and surrogate recovery data.

NYC-WTC_000049916–000049928

Folder label: “GCMS X 1/3/02 A 1/17/02

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NYC 9/11 Public Portal Document Library Search Compound Report Data File : C:\MSDCHEM\1\5973N\02JAN17\31631.D Vial: 3 * Acq On : 17 Jan 2002 11:52 am Operator: Sample : 508 scan Inst : Instrumen Mise : January 17, 2002 Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\MSDCHEM\1...\SCAN508.M (RTE Integrator) Title : 508 scan method Library : C:\DATABASE\WILEY7N.L ********************************************************************* Peak Number 2 Cyclobutaneethanol, .beta.-. Concentration Rank 3 R.T. EstConc Area Relative to ISTD R.T. 4.85 0.19 ug/L 55646 1,4-Dichlorobenzene-d4 9.71 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Cyclobutaneethanol, .beta.-methy... 112 C7H120 116203-80-6 36 2 2-Pentene, 3-methyl-, (Z)- (CAS)... 84 C6H12 000922-62-3 9 3 2-Pentenal, (E)- 84 C5H80 001576-87-0 7 4 2-Butenal, 2-methyl- $$ Crotonal... 84 C5H80 001115-11-3 7 Abundance Scan 129 (4,846 min): 31631 .D (-) m/z 83.95 100.00% 84 55 41 5000

50 i 1 ' • ■ i ■ ■ ■ • i ■ ■ * ■ i ■ 1 ■ ■ i ■ • 4.40 4.60 4.80 5.00 5.20 0: ’1’112111—8311’5711151 mh 1′10112101113110901100010307081771" m/z 55.10 73.91% nz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105110115120 Abundance #13627: Cyclobutaneethanol, .beta.-methylene- 515 81

5000 —p-r-r-r-p-r ■ ■ 1 * • 4.40 4.60 4.80 5.00 5.20 41 69 79 m/z 83.10 68.39%

/z-> 0 TTTTTTTTpT-rTp-rrrjTTT 1’01321157 - L 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105110115120 112 TCIBPnp

Abundance #3467:2-Pentene, 3-methyl-, (Z)- (CAS) $$ (Z)-3-Methyl-2-.. 41 69 4.40 4.60 4.80 5.00 5.20' ‘ 5000 55 m/z 41.10 52.62% 84

I4mm7HH iz-> 0

Abundance T tmpmp Taaam’ 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105110115120

27 #3201:2-Pentenal, (E)- 55 LAAMAL 4.40 m/z 4.60 39.10 4.80 5.00 5.20 42.46% 39 84 5000

50 0 Tth ml TPTTTTTTTTTT 66 I ‘ ‘ ‘ I ‘ ‘ I ' ‘ ' 1 l‘ ‘ 1 ‘ I ' ' m/z—> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100105110115120 4.40 4,60 4.80 5.00 5.20

31631.D SCAN508.M Tue Jan 22 08:36:54 2002 Page 4

NYC-WTC_000049923

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NYC-WTC_000049923Source: NYC Law Department, mirrored locally

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