GCMS analysis results for sample AD31632, February 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File C:\HPCHEM\l\DATA\JAN0302\31632.D Vial: 42 Acq On 5 Jan 2002 2:27 am Operator: 209 GALOS Sample gems scan l/2a Inst : GC/MS 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS1126.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L ********************************************************************* Peak Number 1 2-Butenal, 3-methyl- Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

6.25 0.32 ug/1 68176 1,4-Dichlorobenzene-d4 11.53

Hit# of 5 'entative ID MW MolForm CAS# Qual l 2-Butenal, 3-methyl- 84 C5H80 000107-86-8 53 2 2-Pentenal, (E) - 84 C5H80 001576-87-0 50 3 Furan, 2,3-dihydro-4-methyl- 84 C5H80 034314-83-5 49 4 2-Butenal, 2-methyl - 84 C5H80 ______ 001115-11-3 46 Abundance Scan 131 (6.248 mln): 31632.D (-) m/z 83.90 100.00% 55 84

39 5000 ’’1***I’’I’**I** 6.00 6.20 6.40 6.60 . ......... ..llliMOl.IlllI.... ”...... III..!.,........ 193.... m/z 55.00 81.98% miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 110 Abundance #62726:2-Butenal, 3-methyl- 84

5000 41 55 A4,4MA--- 6.00 6.20 6.40 TA 6.60 m/z 39.05 60.81% 50 . 69 mpmt 1 i i » pi i » i j l > » I J Ki » » | i t i i | T*ug"uunu miz-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105110 Abundance #567: 2-Pentenal, (El- 55 27 39 84 6.00 6.20 6.40 6.60 5000 m/z 41.05 52.91%

|| ■ I 69 I miz-> Abundance 1 rp 11 r 111 n ) 1i1 r| 11i1-] 1i1.J1i1 qi ri q-i Ii q 11 n ri 11 p nq 111 q i il 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105110 #557: Furan, 2,3-dihydro-4-methyl- 55 84 |.U. j ill.

vw m/z 600 6.20 6.40 6.60 82.95 46.21% 5000 41 27 69 50 . *' i * ■ *' i. ■ ■ i ■ ■1 ■ i ■1 • T mh Thmunm—nn—mgvr TEu""nmman‘pi1 m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105110 6.00 6.20 6.40 6.60

31632.D GCMS1126.M Fri Feb 01 11:12:08 2002 Page 1 NYC-WTC_000049730