GCMS analysis results for sample AE08962, May 7, 2002

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Data File : C:\MSDCHEM\l\DATA\020424\08962.D vial: 13 Acq On : 24 Apr 2002 9:39 pm Operator: Nefliu Sample : sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: rteint.e Quant Method : C:\MSDCHEM\1\METHODS\SCAN020424.M (Chemstation Integrator) Title : Method 508 GC/MS Scan Library : C:\DATABASE\nist98.1 ********************************************************************* Peak Number 5 6,2,5-Ethanylylidene-2H-cyc... Concentration Rank 6

R.T. EstConc Area Relative to ISTD R.T.

31.09 0.32 ug/1 559536 Phenanthrene-dl0 31.72 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 6,2,5-Ethanylylidene-2H-cyclobut... 192 C11H12OS 019086-86-3 37 2 1H-1,2,3-Triazole, 4, 5-diphenyl-... 327 C21H17N3O 056701-36-1 33 3 Isoquinoline, 1,2,3,4-tetrahydro... 328 C18H20N2O4 1000128-79-2 33 4 5-[5-Methylfurfurylidene]hydantoin 192 C9H8N2O3 1000214-69-2 25 Abundance Scan 4767 (31.088 min): 08962.D (-4752) (-) m/z 192.10 100.00% 192

5000 40 96 82 132 I | 146160 ■ ■' i ■ ■11 r11 ■11 30.80 31.00 31.20 31.40 ■ ■ i • ■

—Tnr+H i....... 55 , 211 ■ ■ ■ ■ i • •1 ‘ i ■ ■ ’1.** • ■ i ■' 1I—B2netmm*BPOnngr m/z 40.10 33.65% miz-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #80887: 6,2,5-Ethanylylidene-2H-cyclobuta[cd[2]benzothiop... 80 192

5000 39 59 95 113 30.80 31.00 31.20 31.40 m/z 193.10 21.38% +4A 4 Ji 11aaaaaa***2*188** n/z-> 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #80899:1H-1,2,3-Triazole, 4,5-dipheny/-1-(phenylmethoxy)- 192 91 30.80 31.00 31.20 31.40 5000 m/z 96.10 20.19%

105 165

niz-> 40 4363 77 —44- — i

60 544. HH 208 i ■ ■'' । ■ ■ “ । 80 100 120 140 160 180 200 220 240 260 280 300 320 i " 1' i ■ ■

Abundance #81065: Isoquinoline, 1,2,3,4-tetrahydro-1-[2-nitrobenzyr|... 192 APP A....... * * I * ‘ ‘ ' I ' • i 30.80 31.00 31.20 31.40 m/z 146.20 17.48% 5000-

176 ।

/z—> 49 63 78 92 TIIWmmmum 117131/148 162 1 „ 207 222236250264 280 295 311 328 11*—**110npumnttn ' 1 i • 1 1 ■ I • ■ 1 1 1 ' ' ' I ' 1 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 30.80 31.00 31.20 31.40

08962.D SCAN020424.M Thu May 02 14:47:57 2002 Page 7

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