GCMS sample analysis report AE08436, Apr 18 2002

NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\l\DATA\APR1202\8436.D Vial: 25 Acq On : 16 Apr 2002 7:35 am Operator: Sample : gc/ms scan 4/10 fb Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 Toluene Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

6.38 3.71 ug/1 519076 1,4-Dichlorobenzene-d4 12.23

Hit# o Tentative ID MW MolForm CAS# Qual 1 Toluene ) 92 C7H8 000108-88-3 21,3,5-Cycloheptatriene 92 C7H8 000544-25-2 64 3 5-Norbornadiene 92 C7H8 000121-46-0 50 4 Tetracyclo [3.2.0.02,7.04,6] heptane 92 C7H8 000278-06-8 47 Abundance Scan 145 (6.378 min): 8436.D (-) m/z 91.00 100.00% 91

5000

I 1““1 1‘‘|U1‘ )I I I I I I I I ____ I I I I

65 6.00 6.20 6.40 6.60 6.80 39 45 51 i i । i r np , ! i । > i i "T 1 IJ | I > I i 11 ■ i7 I I i | i —14 73 77 85 I I I I 1 I I I I 1 I I I I I I r T m/z 92.00 ■ 61.15% m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #63030: Toluene 91

5000 ' t ' 6.00 6.20 6.40 6.60 6.80 m/z 64.95 10.42% PuuummumTIOTT—1uuT +1 —IP 45 51 61.65 m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 Abundance #63035:1,3,5-Cycloheptatriene 91 ‘I* ■ 1 । 1 1 1 1 । ■ 1 1 । ' ■1 1 । ■ 6.00 6.20 6.40 6.60 6.80 5000 m/ z 39.05 8.95%

65 27 37 46 51 61 . ■ ■।■- > ■।■I■.।■■■ ■ । >!■ ■ 11 > । > 11 > ■ > 11 < > 111 I I I | I I I ! | ITr 111"11" " r " ' i " 111 " i1" ■ ।" m/z-> 20 25 30 35 40 45 50 55 60 65 70. 75 80 85 90 95 100 Abundance #63032: 2,5-Norbornadiene r-p-r ............ /....................... 91 6.00 6.20 6.40 6.60 6.80 m/ z 62.95 6.96%

5000 66

27 41 51 110 "'I11"!' I I I I 62 I I I I _ I I I [ I r I I IY I I I I I I I I I I I 1 I ] 111" 111 " __________ i ] ft — । - /______ ii । । ...____ । “ |U i । । । । । । it r ।

m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 6.00 6.20 6.40 6.60 6.80

8436.D GCMS0412.M Wed Apr 17 09:48:30 2002 Page 1 NYC-WTC_000048578