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GCMS analysis results, Sample AE08262, April 22, 2002

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GCMS analysis report for sample AE08262 showing surrogate recovery and unknown compound screening on April 22, 2002.

NYC-WTC_000048309–000048332

Folder label: “GCMS X 4/9/02 A 4/17/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\l\DATA\020417\08262.D Vial: 19 Acq On : 18 Apr .2002 12:18 am Operator: Nefliu Sample : sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 2 Boron trifluoride etherate Concentration Rank 14

R.T. EstConc Area Relative to ISTD R. T.

3.95 0.21 ug/L 206933 1,4-Dichlorobenzene-d4 9.99

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Boron trifluoride etherate 142 C4H10BF3O 000109-63-7 2 2 Ethyl Chloride 64 C2H5C1 000075-00-3 2 3 Cyclopropane, (bromomethyl)- 134 C4H7Br 007051-34-5 1 4 2,2'-Bioxirane, (R*,R*)-(.+/-.)- 86 C4H602 000298-18-0 1 Abundance Scan 148 ( 3,949 min): 08262.D (-142) (-) m/z 49.00 100.00% 49 55 38 5000

85 3 60 3 80 4.00 4 20______ 0^ .................... I, I— ' ' I ' 1 1 1 I ' ■ ' ' I ' ' 1 1 1 1 ' ____________________________ m/z 48.05 76.03% n/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 140 Abundance #1099. Boron trifluoride etherate 31

59 5000- 45 74 3 60 3.80 4.00 4.20 m/z 55.10 73.63% 15 n/z—> 0- - 10 20 —25ll30 +394444 40 50 66 11''11 1 60 70 81 93 ''l ' ' ‘ 1 I ' ' 80 90 100 110 120 127 130 140 Abundance #107943: Ethyl Chloride

3.60 3 80 4 00 4 20 64 5000 m/z 51.00 66.44%

49

n/z- > 0- .....10 15 11I 20 30 + 35

40 50 60 70 80 90 100 110 120 130 140 Abundance #12820: Cyclopropane, (bromomethyl)- 55 3 60 3.80 4.00 4.20 m/z 37.90 53.77%

5000 27 39

m/z—> 0 14 Pri 1 1 1 „Il, ' 1 I# 10 20 30 40 IP 60 70 80 93 106 121........136 90 100 110 120 130 140 11Pmm 3.60 3.80 4 00 4 20

08262.D 041702SCAN.M Thu Apr 18 09:49:31 2002 Page 7

NYC-WTC_000048319

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NYC-WTC_000048319Source: NYC Law Department, mirrored locally

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