GCMS analysis report sample AE09677, May 23, 2002

NYC 9/11 Public Portal Document

Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\052102\9677.D Vial: 15 Acq On : 22 May 2002 12:44 am Operator: Mclean Sample : re-extract Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\052202.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 2 Boron trifluoride etherate Concentration Rank 15 R.T. EstConc Area Relative to ISTD R.T. 3.78 0.48 ug/L 338884 1,4-Dichlorobenzene-d4 9.90 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Boron trifluoride etherate 142 C4H10BF3O 000109-63-7 2 2 Ethyl Chloride 64 C2H5C1 000075-00-3/1 3 Acetic acid, chloro-, ethyl ester 122 C4H7C1O2 000105-39-5 1 4 Borane, trifluoro- 68 BF3 007637-07/2 1 Abundance Scan 118 (3.773 min): 9677.D (-117) (-) m/z 49.10 100.00% 49

5000 86 40 3.40 3.60 3.80 4.00 4.20 58 1 0- ■ i • ■ ■ ■ i ■ • ■ ■ i • • ■ ■ i ■ ■ • ■ i' ■ m/z 51.10 29.96% miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #1099: Boron trifluoride etherate 31

59 5000 45 74 340 3.60 3.80 4.00 4.20 m/z 86.00 22.78% 0- * • i > 15.251 T 1 ■ 39,1,1 ■ ■ t'166111' ,81 93 127 ■1 i ■ ■ ■ ■ i ■ ‘ • ■ i ■ ■1 ‘ i 1 1 ■ ■ i ■ ■ ■ ■ i ■ ■ miz-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #107943: Ethyl Chloride 23

3.40 3.60 3.80 4.00 4.20 64 m/z 47.10 13.12% 5000 /*. 49 35 15 I 0-- 1 Im, i ■ ■ ''n1' ■ ■ ‘T1' ‘ i ■ • ‘ ■ i ■ * ■ ■ i ■ • ‘ ■ I ■ ■ ■ ■ I ‘ •1 ■ i • ■ ■ ■ i ■1 n/z-> 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #108005: Acetic acid, chloro-, ethyl ester 23 340 3.60 3.80 4.00 4.20 m/z 50.00 13.03%

5000

14 42 49 77 mwtodMobune miz—> 0J lo +35— 11+4459.65—— 10 20 30 40 50 60 70 | 80 88 94 ■ 1 1 1 < • • • । • i"1 > i > ■ 90 100 107 । ■ ■ ■ ■ । । ■ • ■ । ■ ■ 110 122 120 130 3.40 3.60 3.80 4.00 4.20

9677.D 052202.M Wed May 22 11:34:06 2002 Page 5

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