GCMS analysis results for unknown compounds, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\1\DATA\060702\12737.D Vial: 13 Acq On 7 Jun 2002 6:21 pm Operator: Sample Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L Peak Number 8 Borane, trifluoro- Concentration Rank 11 R.T. EstConc Area Relative to ISTD R.T. 4.34 0.77 ug/L 424169 1,4-dichlorobenzene-d4 9.89 Hit# Of 5 Tentative ID MW MolForm CAS# Qual

1 Borane, trifluoro- 68 BF3 007637-07-/ 2 2 Boron trifluoride etherate 142 C4H10BF3O 000109-63-7 2 3 Ethyl Chloride 64 C2H5C1 000075-00-3 2 4 2-Chloroethanol 80 C2H5C1O 000107-07-3 1 Abundance Scan 215 (4.343 min): 12737.D (-213) (-) m/z 49.10 100.00% 49 84

5000

■ ■ i ■ ■ ■ ■ i ■ ■ ' ■ i ' ' 1 1 1 1 1 1 1 1 1 42 4.00 4.20 4.40 4.60 0- ----- I ■ ■ • • । ■ j ■ ■ > ■ 11 m/z 84.00 92.92% m/z-> 0 10 20 30 40 50 60 70 80 90 100 110 120 130 Abundance #12321: Borane, trifluoro- 49

5000 ' * ■ । * i * > । i i * * । ■ । * ■ । * ■ ■ ■ । । 4.00 4.20 4.40 4.60 m/z 50.05 25.22%

n/z-> 0-—00——

Abundance 0 11 1? 30 38 10 20 30 40 50 60 70 80 - 90 #1099: Boron trifluoride etherate 31 68 -■ ' i ■ 100 110 120 130 "Mpmts. 59 4.00 4.20 4.40 4.60 5000 45 m/z 48.00 20.24% 74 "...

miz-> 0- 0 521 10 20 30 66 t , 39,1,1, . . C. THTT 70 40 50 IT 60 .81 ■ 1 i ‘ 80 93 ...................... 127 ■ i ■ ‘ 90 100 110 120 130 Abundance #107943: Ethyl Chloride 1 1 i 1 ■ ■ ■ i ■ • ■ ■ i ' ■ • 1 i ■ ■ ■ ■ i ■ 23 4.00 4.20 4.40 4.60 m/z 51.10 18.25% 64 5000

49 35 n/z-> 0- * 0 15 10 20 H 1——#41 30 40 50 60 70 80 90 100 110 120 130 ■ ' i ‘ 4.00 ■ i • ■ ■ ■ । ' 1 ■ • । ‘ 4.20 4.40 4.60 • i ■

12737.D 060302.M Mon Jun 10 11:24:06 2002 Page 11

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