GCMS analysis results for unknown compounds, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\1\DATA\060702\12737.D Vial: 13 Acq On 7 Jun 2002 6:21 pm Operator: Sample Inst : Instrumen Mise : Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 7 Isocrotonic acid Concentration Rank 4 R.T. EstConc Area Relative to ISTD R.T. 4.10 3.54 ug/L 1956890 1,4-dichlorobenzene-d4 9.89 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 Isocrotonic acid 86 C4H602 000503-64-0/9 2 2(3H)-Furanone, 3-(2-bromoethyl)... 192 C6H9BrO2 054815-24-6 9 3 N,N-Diethyl-llH-indolo[3,2-c]qgi... 317 C21H23N3 1000212-55-4 9 4 2-Butenoic acid, (E)- 86 C4H602 000107-93/7 7 Abundance Scan 174 (4.102 min): 12737.D (-172) (-) m/z 86.00 100.00% 86

5000

41 55 103 1 ■ ‘ । ■ 1 1 i1 ■ ' 1 i 1 ■ 1 ■ i 1 1 ' ■ i 3.80 4.00 4.20 4.40 ol । ’tr++t.tt 1T’trT1 ■ ■ i ■ ■ ■ ■ i ■ ■ ■ • i ■ ■' ■ i ■ ■ ■11 ■ ■ ■111 ■ ■ ■ i ■ ■ ■ ■ i ■ ■ ‘ ■ i ■'1' i ■ ■ ■ ■ i ■' ■ ■ i' ■ m/z 84.00 36.23% u/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 Abundance #34646: Isocrotonic acid 39 85

5000 68 ■ ■ ■ i ■ 1 ■ ■ । ■ ■ ■ ■ । 1 ■ 1 ■ । ■ ■ ■ ■ i 3.80 4.00 4.20 4.40 m/z 87.95 34.43%

mfe-> Abundance 0 20 140 60 lm ...... .......... 80 100 120 140 160 180 200- 220 240 260 280 300 320 #34747:2(3H)-Furanone, 3-(2-bromoethyl)dihydro- haako/ 86 ■ ■ ' i ■ ■ ■ ' i ■ ■ ■ ■ i ' ‘ ■ I 1 • I

3.80 4.00 4.20 4.40 5000 m/z 89.10 26.42% 55 27 69 107 129 184 01 - ‘ 1‘--A1AA*‘1‘*AA1**‘‘I‘*+*I‘‘‘‘I‘++II‘‘I+L‘UIII‘‘AII‘‘IIII‘ n/z-> Abundance 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 #34936: N,N-Diethyl-11 H-indolo[3,2-c]qginoline-11-ethanamine 86 ' ■ ■ i ' 1 ■ '.1 1 3.80 4.00 I....... ' v r1 1 1 1 1 1 ' 1 1 1 4.20 4.40 m/z 41.10 19.25% 5000 "Wy"Amhsash 42 58 44 - 109 128 151 176 203 231 246 262 317 0 ■ ■ । •1 , , fl 1 > "I , . . ’ । ’1 . . । . I . . । . I , . | . , I > | ■ . . 1 । . . . , । . . . ,'| . 11 > । T i t > । > i > । | 1 | I | | | > | r | | i ■ ■ i ‘ ■ i ■ ■ ■ 1 i ■ ■ ■ ■ i ■ ■ ■ ■ i m/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 3.80 4.00 4.20 4.40

12737.D 060302.M Mon Jun 10 11:24:04 2002 Page 10

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