GCMS results sample AE08257, April 2002

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Library Search Compound Report

Data File C: \MSDCHEM\1\DATA\020417\08257 . D Vial: 15 Acq On 17 Apr 2002 9:01 pm Operator: Nefliu Sample sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 11 Cyclic octaatomic sulfur Concentration Rank 9

R.T. EstConc Area Relative to ISTD R.T.

26.58 0.23 ug/L 345211 Phenanthranene- dl 0 23.02 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Cyclic octaatomic sulfur 256 S8 010544-50-0 94 2 Ethyl Chloride 64 C2H5C1 000075-00-3 4 3 Ethene, 1,2-difluoro- 64 C2H2F2 001691-13-0 3 4 Sulfur dioxide 64 02S 007446-09-5 3 Abundance Scan 3999 (26 576 min): 08257 D (-3989) (-) m/ z 64.00 100.00% 64

5000 128 160 96 192 256 V 40 26 20 2640 26.60 26 80 27 00 0+ — 84, , I, I.............. q-> r. . I I <—» J__ m/z 127.90 28.77% ■ ' i ' ' IB33 n/z- > 20 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #113565 Cyclic octaatomic sulfur 64

5000 H v 26 20 26 40 26.60 26 80 27 00 m/z 159.80 25.16% 32 128 256

n/z- > 01 ' I ' ' 1 ' 1 1 ' 1 1 I 20 40 60 L +119.... 80 96

100 120 140 160 160 192 1. 224 TIII———amT 180 200 220 240 260 H Abundance #20621: Ethyl Chloride 28 64 ' i ' 1 ' ■ i ' ■ ' ' i 1 26 20 2640 26 60 26 80 27 00 5000- m/z 255.80 21.40% 49

0+ ,114 110 n ■ ' i 1 ■ ■ i ■ ' 1 1 i ' ■ ■ ' i ' ■ ■ 1 i ' 1 1 r i ■ ■ ■ ■ i 1 ■ ■ ■ i ■ ■ ■ ■ i 1 ■ ‘ ■ i ■ ' ■ ■ i ■ ' n/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 Abundance #20626 Ethene. 1.2-difluoro- TT 61 26 20 2640 26 60 26 80 27 00 m/z 191.80 18.63% 45 5000- 31

14 o- ‘II 1 n/z-> 20 40 60 80 100 120 140 160 180 200 220 240 260 26 20 26 40 26.60 26 80 27 00

08257.D 041702SCAN.M Thu Apr 18 09:33:59 2002 Page 16

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