GCMS results sample AE08254, April 2002

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Library Search Compound Report Data File : C:\MSDCHEM\1\DATA\020417\08254 .D Vial 12 Acq On : 17 Apr 2002 6:32 pm Operator Nefliu Sample : sample Inst Instrumen Mise Multiplr 1.00 MS Integration Params: LSCINT.e

Quant Method C:\MSDCHEM\1\METHODS\041702SCAN.M (Chemstation Integrator) Title 508 Modified GC/MS scan Library C:\DATABASE\NIST98.L ********************************************************************* Peak Number 3 2,5-Dihydrophosphole, 3-met.. Concentration Rank 5 R.T. EstConc Area Relative to ISTD R.T. 22.64 0.32 ug/L 542178 Phenanthranene-dl0 23.02 Hit# of 5 Tentative ID MW MolForm CAS# Qual 1 2,5-Dihydrophosphole, 3-methyl-1... 192 C11H13OP 1000196-97-5 45 2 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 42 3 4-Hydroxy-3,5-dimethylcinnamic acid 192 C11H1203 1000132-15-8 38 4 1,5-Naphthalenedithiole 192 C10H8S2 1000223-69-5 38 Abundance Scan 3330 ( 22,645 min) 08254.D (-3320) (-) m/z 192.10 100.00% 192

5000

146 160 22 40 22 60 22.80 23 00 40 5 2 70 82 118 01 ............ ............................... 11-1 H 111111111! mmmp 11 pa i ■ ■ ■ i‘| ■ ■ ■ ■ i ■ > ........ Ill ■ ■ । . m/z 191.10 20.71% Tl/Z--> 20 30 4.0 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80965. 2,5-Dihydrophosphole, 3-methyl-1-oxo-1-phenyl- 192 164

5000 99 115 22 40 22 60 22 80 23 00 47 77 177 m/Z 146.10 14.46%

TT/Z—> 01 20 27 30 39 67 125 134 H H 11 1.. I l, n + 91 „ +1072111711,41.47 40 50 146 +4454., 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 I ’".......... 1 ■ I ■ ■ A Abundance #80870. Thiocyanic acid, 2-benzothiazolyl ester 192 I A ' • I I UiB. 22.40 22.60 22 80 23 00 5000 m/z 193.00 11.03%

. T 82 90 108 134

Tl/Z--> 04 20 30 40 45

50 H TH | 148 160 122 I. I. ■ I... 11 ■| ......... ........... 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 T‘ Abundance #81030: 4-Hydroxy-3.5-dimethylcinnamic acid 192 22 40 22 60 22.80 23.00 m/z 160.10 10.40% 5000

89 175 63 45 55 1 77 117 145

n/z-> 0 20 30 I vv ----- ' I " 111 40 50 60 I

70 11

80 , Q97 105I ill. 163 TTTH54 90 100 110 120 130 140 150 160 170 180 190 200 + 1— IT‘II1‘*I‘T 2240 22.60 22.80 23.00

08254.D 041702SCAN.M Thu Apr 18 09:23:29 2002 Page 8

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