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GCMS analysis results for sample AE07979, Apr 2002

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Laboratory report documenting the GCMS analysis of sample AE07979 including surrogate recovery data and unknown compound screening on April 18, 2002.

NYC-WTC_000046722–000046739

Folder label: “GCMS X 4/5/02 A 4/16/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\MSDCHEM\1\DATA\020415\07979.D Vial: 19 Acq On : 16 Apr 2002 1:32 am Operator: Nefliu Sample : sample Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C: \MSDCHEM\1\METHODS\041202SCAN.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 9 4-Hydroxy-3,5-dimethylcinna... Concentration Rank 10

R.T. EstConc Area Relative to ISTD R.T.

22.64 0.21 ug/L 256897 Phenanthranene-dl0 23.02 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 4-Hydroxy-3,5-dimethylcinnamic acid 192 C11H1203 1000132-15-8 42 2 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 42 3 3-(2-Methoxy-5-methylphenyl)acry. . . 192 C11H1203 103986-76-1 40 4 Thiocyanic acid, 2-benzothiazoly... 192 C8H4N2S2 006011-99-0 40 Abundance Scan 3330 (22 645 min): 07979 D (-3320) (-) m/z 192.30 100.00% IS 2

5000

82 96 146 160 22.40 22.60 22.80 23 00 40 4g 70 120 0 --mmPP 4 n. । jJ....... r ... ml . m/z 191.30 20.27% n/z—> Abundance 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 #31030 4-Hydroxy-3,5-dimethylcinnamic acid 192 I 5000 22 40 22 60 22 80 23.00 89 175 m/z 146.30 14.44% 63 45 55 J 77 117 145

| +27/195, Irguu rr I , 135 h 163 n/z-> 0- 30 ....40ploli, TITtTpr TT 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80953' 2-Propenal, 3-(3,4-dimethoxyphenyl)- 192 161 ................... .... 2240 22 60 22.80 23.00 5000- m/z 193.30 13.33% 77 121 149 177 91 103 138 0- . .... Li....l,i.................. +1 /Z—> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80954: 3-(2-Methoxy-5-methylphenyl)acrylic acid 161 192 22 40 22 60 22.80 23.00 m/z 160.30 12.35% 5000 105 77 132 91 115 145 39 51 65

/z—> 0 -lpll 30 — 40 50 60 70 80 90 421l —PPP L —l+ 1122 .

100 110 120 130 140 150 160 170 180 190 200 175 * 1 i |T.......23.00 22 40 22.60 22 80 1

07979.D 041202SCAN.M Tue Apr 16 13:48:32 2002 Page 12

NYC-WTC_000046737

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NYC-WTC_000046737Source: NYC Law Department, mirrored locally

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