DEP water sample drip rate log, June 2002

NYC 9/11 Public Portal Document Library Search Compound Report Data File C:\MSDCHEM\l\DATA\060602\603LB.D Vial: 3 Acq On 6 Jun 2002 12:57 pm Operator: McLean Sample 6/3 eh Inst : Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\060302.M (Chemstation Integrator) Title : 508 Modified GC/MS scan ' * Library : C: \DATABASE\NIST98 . L Peak Number 17 4-Hydroxy-3,5-dimethylcinna ... Concentration Rank 17 R.T. EstConc Area Relative to ISTD R.T. 22.53 0.25 ug/L 284120 Phenanthranene-dl0 22.91 Hit# of 5 Tentative ID MW MolForm CAS# Qual l 4-Hydroxy-3,5-dimethylcinnamic acid 192 C11H1203 1000132-15-8 64 2 5H-Dibenzo[a,d]cycloheptene 192 C15H12 000256-81-5 45 3 2,5-Dihydrophosphole, 3-methyl-l... 192 C11H13OP 1000196-97-5 45 4 2-Propenal, 3-(3,4-dimethoxyphen... 192 C11H1203 004497-40-9 38 Abundance Scan 3311 (22.533 min): 603LB.D (-3304) (-) m/z 192.00 100.00% 192

5000

miz-> 0 mmmmmpm 44 70 82 96 118 146 160 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 + 22.20 22.40 22.60 22.80 m/z 191.00 21.69% Abundance #81030:4-Hydroxy-3,5-dimethylcinnamic acid 192

5000 22.20 22.40 22.60 22.80 175 m/z 193.00 15.18% 63; 89 117 145 45 77 163 105 11’ 135 | niz-> 0 ----- 444 TTpppT 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 U Abundance #80999:5H-Dibenzo[a,d]cycloheptene 192 • ■ i ■ ■ ■ ■ i ■ ■ ■ ■ i 22.20 22.40 22.60 22.80 177 m/z 146.10 5000 14.19% 89 165 39 51 63 76 102 115 128 139 152 | „ o!------- T’It niz-> 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Abundance #80965: 2,5-Dihydrophosphole, 3-methyl-1 -OXO-1 -phenyl- 19/2 22.20 22.40 22.60 22.80 164 m/z 160.00 9.30%

5000 99 115 47 77 177 67 125,34 146 n/z—> Ol 44 457,4444A4A 444L+4455, hyngand 4 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 22.20 22.40 22.60 22.80

603LB.D 060302 .M Mon Jun 10 10:20:51 2002 Page 20

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