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GCMS analysis results for unknown compounds, sample AE09093, May 2002

Machine-extracted title · confidence 95%

Laboratory report showing gas chromatography-mass spectrometry results for unidentified organic compounds in sample AE09093 on May 10, 2002.

NYC-WTC_000044902–000044925

Folder label: “GCMS X 4/30/02 A 5/8/02

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NYC 9/11 Public Portal Document Library Search Compound Report

Data File C:\MSDCHEM\1\DATA\050802\9093.D Vial : 15 Acq On 9 May 2002 2:49 am Operator: Mclean Sample 4/30 eh Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L

Peak Number 13 6H-Dibenzo[a,g]quinolizine ,... Concentration Rank 3

R.T. EstConc Area Relative to ISTD R.T.

36.48 0.68 ug/L 534012 Perylene-dl2 34.70 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 6H-Dibenzo[a,g]quinolizine, 5,8,... 355 C21H25NO4 002934-97-6 10 2 6H-Dibenzo[a,g]quinolizine, 5,8,. 355 C21H25NO4 002934-97-6 9 3 5H-Isoindolo [1,2-b] [3]benzazepin.. . 355 C20H21NO5 055228-79-0/3 4 Pyrido[2,3-d]pyrimidin-4(1H)-one 147 C7H5N3O 024410-19/3 2

A1 Abundance Scan 5684 (36.476 min): 9093.D (-5683) (-) m/z 147.10 100.00% 147 355 96 282 36 205 5000 429 I I I | I I I I | I I I I I > ’ B I I ! I r

36.20 36.40 36.60 36.80 O-rr TTT TT‘ 1u0I0—O—u—I——u]————0O——————0TOOOIRBITOIITI7 m/z 355.10 70.78% m/z-> Abundance 40 60 80 100120140160180200220240260280300320340360380400420 #128845: 6H-Dibenzo[a,g]quinolizine, 5,8,13,13a-tetrahydro... 3$5 1 149 _______ W________________ 5000 T 1 | I-1 1 T | kl I Ti i l < I | i 1

36.20 36.40 36.60 36.80 190 324 m/ z 149.10 66 .23% 77 121

m/z--> 44 Onudinn 1’ +9+44 168 1 220238 264 294. 1111111। ' i 11 n 11 । r । ।Tj। n11 r11 r j i

40 60 80 100120140160180200220240260280300320340360380400420 n | i ri1 | r । 111" I" " I ‘" 11

Abundance #67163: 6H-Dibenzo[a,g]quinolizine, 5,8,13,13a-tetrahydro-... 149 355 T I I I 1 1 1 I I 36.20 36.40 36.60 36.80 5000 m/z 357.10 66 .23% 190 121 77 324 51 0- -mm | 168 TT 222 250 280 306 22 TTT|t 1 i 1" 11 iTj iTi i |Ti । iy ri It111111 TTTTTp-rrq- m/z-> 40 60 80 100120140160180200 220 240 260 280 300 320 340 360 380 400 420 Abundance #103467: 5H-lsoindolo[1 2-b][3]benzazepin-5-one, 7,8,13,13... 355 36.20 36.40 36.60 36.80 m/z 96.10 64.29%| 5000 163 337

192

/z-> 0 <> । > 11111111111111111111111111 111" 11 ■ ” i"11 r'" 11 40 60 80 100120140160180200220240260280300320340360380400420 । 11 > । । 11 । ‘ 11 11 i 11 Ulf | 36.20 36.40 36.60 36.80 1 r1 ' ' ' I

9093.D 050102.M Thu May 09 13:33:39 2002 Page 16

NYC-WTC_000044922

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NYC-WTC_000044922Source: NYC Law Department, mirrored locally

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