GCMS calibration table for TCLP analysis, April 2002

NYC 9/11 Public Portal Document

Data File : C:\HPCHEM\1\DATA\APR2 502\9336.D Vial: 13 Acq On : 26 Apr 2002 12:21 am Operator: Sample : gc/ms scan 4/18 fb Inst : 209 Mise : Multiplr: 1.00 MS Integration Params: LSCINT.P Quant Method C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title 209 625/TCLP calibration table Library C:\DATABASE\NBS75K.L

Peak Number 2 Phenanthrene-dlO Concentration Rank 2

R.T. EstConc Area Relative to ISTD R.T.

25.72 0.21 ug/1 45873 Phenanthrene-dl0 25.58 Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 Phenanthrene-d10 // 188 C14D10 001517-22-2 74 2 Anthracene -diO- A 188 C14D10 001719-06-8 50 3 Naphthalene, 2,6-dimethoxy- 188 C12H1202 005486-55-5 40 4 Naphthalene, 1,7-dimethoxy-______ 188 C12H1202 005309-18-2 36 Abundance 7 Scan 2252 (25.722 min): 9336. D (-) m/z 188.10 100.00% 188

5000 1 । | । । 4 । t । r i । । [ । । । । । । । r

80 94 25.40 25.60 25.80 26.00 40 52 ] ■ - ■ ■ I ■ • ■ ■ i - ■ ■ ■ । ■ ■ ■ ■ । ■ 158 H|""|II"। TVTTIIWWTIUTTTTTTIIr HL m/z 189.10 14.50% m/z-> Abundance 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 #19958: Phenanthrene-d10 1 188

5000 — 25.40 25.60 25.80 26.00 m/Z 184.00 14.23% 80 94 160 66 m/z-> 30 40 50 60 70 A i ■ ■ ■ ■ । ■ ■ ■ ■ । ■ ■ ■ ■ । ■ ■ ■ ■ । ■ 111. . ...... Il... 80 90 100 110 120 130 140 150 160 170 180 190 Abundance #19957: Anthracene-d10- 188 1 ......... I I I l t I ......................... I l li [ I I I 1 I I I I 1 I

25.40 25.60 25.80 26.00 5000 m/Z 80.05 13.29% ft 80 94 160 66 *1 4 n । । I I । - n । । । 1 ■ ■ ■ ■ । ■ ■ ■ ■ । ■ ■ ■ ■ । ■ I ■ i ■ ■ ■ i1111 r 11111 m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 i । [ । । 4 । i । r । । । । । । [ । । । i r Abundance #19908: Naphthalene, 2,6-dimethoxy- 188 25.40 25.60 25.80 26.00 , 173 m/ Z 94.00 9.23% 145 5000 102 114 130 76 94 1 1 1 I I I ■ I 1 I I I I I I I I I I I I I I I I I ‘11111 ■ ■ r 1 " i'''111'r 11 157 .......... /........................... r' i111111''11'1' 11' ■ ' | 1 1 1 ' | T ' ‘ | । 1 | । 1 ■ > | m/z-> 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 25.40 25.60 25.80 26.00

9336.D GCMS0412.M Fri Apr 26 07:55:23 2002 Page 2

NYC-WTC_000044729