GCMS analysis results for sample AE10134, May 8 2002

NYC 9/11 Public Portal Document

’Data File C:\MSDCHEM\1\DATA\050202\10134 .D vial: 26 Acq On 3 May 2002 9:42 am Operator: Mclean Sample 4/29 ad Inst Instrumen Mise Multiplr: 1.00 MS Integration Params: LSCINT.e

Quant Method : C:\MSDCHEM\1\METHODS\050102.M (Chemstation Integrator) Title : 508 Modified GC/MS scan Library : C:\DATABASE\NIST98.L ********************************************************************* Peak Number 13 1,2-Propadiene Concentration Rank 5

R.T. EstConc Area Relative to ISTD R.T.

31.49 0.37 ug/L 242669 Chrysene-dl 2 30.81

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 1,2-Propadiene 40 C3H4 000463-49-0 4 2 Bicyclo[3.3.1]nonan-3-one, 7-(am... 167 C10H17NO 056701-31-6 2 3 Hydrazinecarboxylic acid, ethyl ... 104 C3H8N202 004114-31-2 1 4 Hydrazinecarboxylic acid, ethyl ... 104 C3H8N202 004114-31-2 1 Abundance Scan 4835 (31.488 min): 10134.D (-4833) (-) m/z 40.10 100.00% 40

5000

104 207 71 84 167 ___ 31.20 31.40 31.60 31.80 57 - 1 i ' ' ' i 1 1 1- m/Z 2 07.00 17.05% m/z-> 20 40 60 80 100 120 140 160 180 200 Abundance 43 #1401: 1,2-Propadiene I N NN 4 5000 II ill WUII. 31.20 31.40 31.60 31.80 m/ z 104.00 14.02% 12 26 . | H— m/z-> 20 40 60 80 100 120 140 160 180 200 Abundance #910: Bicyclo[3.3.1]nonan-3-one, 7-(aminomethyl)- 30 95 I . JI ,I...... r , , I , r'-r * ri ■ ■ r ■ F1 1 31.20 31.40 31.60 31.80 5000 m/ Z 36.10 12.05% 110 138 41I — - 80 167 124

m/z-> 55 or । —T , , 1, . tl—s plpl, 1.n. , il 20 40 60 80 100 + , ............... — 1 I ■ ■ 1 1 1 1 1 ' 1 1 1 ' 1 ' 1 1 120 140 160 180 200 | Abundance #108039: Hydrazinecarboxylic acid, ethyl ester 1t Tl TB 31.20 31.40 31.60 31.80 m/z 71.10 6.29% 45 5000

59 104 76 Tn 'V' ' ' I I ' 1 ' i 1 ' m/z-> 40 60 80 100 120 140 160 180 200 31.20 31.40 31.60 31.80

10134.D 050102.M Mon May 06 12:24:22 2002 Page 16

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