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GCMS calibration data for method 508, April 23 2002

Machine-extracted title · confidence 100%

Calibration data for GCMS analysis of volatile organic compounds recorded on April 23, 2002.

NYC-WTC_000044313–000044337

Folder label: “GCMS X 4/23/02 A 4/26/02

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NYC 9/11 Public Portal Document

Library Search Compound Report

Data File : C:\HPCHEM\1\DATA\APR2 202\8757.D Vial: 13 Acq On : 22 Apr 2002 8:55 pm Operator: Sample : gc/ms scan 4/11 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: LSCINT.P

Quant Method : C:\HPCHEM\1\METHODS\GCMS0412.M (RTE Integrator) Title : 209 625/TCLP calibration table Library : C:\DATABASE\NBS75K.L

Peak Number 1 2-Heptene Concentration Rank 10

R.T. EstConc Area Relative to ISTD R.T.

7.16 0.33 ug/1 43339 1,4-Dichlorobenzene-d4 12.21

Hit# of 5 Tentative ID MW MolForm CAS# Qual

1 2-Heptene 2 4-Penten-2-one, 4-methyl- 98 98 C7H14 C6H10O 000592-77-8 43 003744-02-3 38 3 Hexanal 100 C6H120 000066-25-1 35 4 2-Heptene, (E) -______________ 98 C7H14 014686-13-6 30 Abundance Scan 231 (7.164 min): 8757.D (-) m/z 55.00 100.00% 44 55 83

39 5000 98 72 —A /. TM, ... 50 67 6.80 7.00 7.20 7.40 7.60 | I । I l | 1 I > I | I I t r | i t i 11" " r1" i' ■ i" " i" " i'1 11" " i'1 m/ z 82.95 98.44% m/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #1337: 2-Heptene 41 56

5000 69 1 1 । 1 1/ 1 .... 1 i 1A 1 ' । .... ' 1 ' 1 ....... i ' ' 1 1 i ' 27 98 680 7.00 7.20 7.40 7.60 m/z 43.95 90.77% I I I I I I I 1 83 I I r I ■ I I I I I I I I I I I I II I I I I I I I r I 11" " I " " i " 1' 11 111 " " i TIIT n/z-> 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 Abundance #1244: 4-Penten-2-one, 4-methyl- 43 I I I I I I I fl- I I I I I I I I I I ( I I I-

680 7.00 7.20 7.40 7.60 5000- m/z 56.00 80.93%

83 29 39 98

m/z-> p ■ ! | ! I ! I | ! l ! । | ! I > ' | I ■ I I | । I

20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 ITT

Abundance #1573: Hexanal 1 i 1 ' 1 ' 1 1 ' ' 1 i ' A 44 680 7.00 7.20 7.40 7.60 56 m/ z 43.00 79.60%

5000 27 72 82 67 APw WMM m/z-> '11" 1' i ‘ " i " " 11" 11 0 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100 105 " i''111 111 ■ ■ -111 >' 1111 100 11 ’1' J " " I " " f 1 6.80 7.00 7.20 7.40 7.60

8757.D GCMS0412.M Tue Apr 23 08:22:53 2002 Page 1

NYC-WTC_000044319

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NYC-WTC_000044319Source: NYC Law Department, mirrored locally

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