GCMS calibration reference data for sample REFA1, April 2002

NYC 9/11 Public Portal Document

r

Quantitation Report (QT Reviewed)

Data File C:\HPCHEM\1\DATA\APR18 02\REFAl.D Vial: 17 Acq On 19 Apr 2002 3:35 am Operator : Sample GC/MS SCAN 3/26 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: Apr 19 14:55 2002 Quant Results File: GCMS0419.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0419.M (RTE Integrator) Title Last Update : : 209 625/TCLP calibration table Fri Apr 19 14:51:24 2002 C Response via DataAcq Meth

Internal Standards : : Initial Calibration GCMS0412

R.T. Qlon Response vA Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.21 152 666073 20.00 ug/1 -0.03 10) Naphthalene-d8 15.85 136 2437751 20.00 ug/1 -0.03 17) Acenaphthene-diO 21.16 164 1364607 20.00 ug/1 -0.02 30) Phenanthrene-dlO 25.59 188 2029547 20.00 ug/1 -0.03 39) Chrysene-dl2 33.65 240 1414866 20.00 ug/1 -0.03 45) Perylene-dl2 37.87 264 949178 20.00 ug/1 -0.04

System Monitoring Compounds 28) TCMX 23.29 209 25823 2.27 ug/L -0.04 Spiked Amount 4.000 Recovery = 56.75% 38) 2,4-DDD 0.00 235 0 0.00 ug/mL Spiked Amount 5.000 Recovery = 0.00%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.86 74 73566 5.07 ug/1 98 3) bis(2-Chloroethyl )ether 11.61 93 182818 8.10 ug/1 98 4) 1,3-Dichlorobenzene 12.11 146 127371 5.47 ug/1 95 5) 1,4-Dichlorobenzene 12.26 146 132255 5.65 ug/1 98 6) 1,2-Dichlorobenzene 12.77 146 133253 6.13 ug/1 98 7) 2,21-oxybis(1-Chloropropan 13.09 45 243881 7.82 ug/1 100 8) N-Nitroso-di-n-propylamine 13.48 70 119188 8.05 ug/1 97 9) Hexachloroethane 13.62 117 38294 4.46 ug/1 96 11) Nitrobenzene 13.89 77 161399 7.55 ug/1 100 12) Isophorone 14.54 82 308245 7.62 ug/1 99 13) bis(2-Chloroethoxy)methane 15.22 93 220973 8.39 ug/1 100 14) 1,2,4-Trichlorobenzene 15.73 180 114745 6.19 ug/1 99 15) Naphthalene 15.90 128 433786 7.40 ug/1 99 16) Hexachlorobutadiene 16.45 225 49522 5.34 ug/1 97 18) Hexachlorocyclopentadiene 18.64 237 9733 1.61 ug/1 94 19) 2-Chloronaphthalene 19.40 162 263419 7.32 ug/1 98 20) Dimethylphthalate 20.49 163 411663 9.92 ug/1 99 21) 2,6-Dinitrotoluene 20.71 165 79620 8.03 ug/1 99 22) Acenaphthylene 20.68 152 401094 7.97 ug/1 99 23) Acenaphthene 21.24 153 288896 8.07 ug/1 99 24) 2,4-Dinitrotoluene 21.87 165 101508 7.77 ug/1 97 25) Diethylphthalate 22.62 149 375759 9.44 ug/1 99 26) 4-Chlorophenyl-phenylether 22.78 204 158375 8.97 ug/1 96 27) Fluorene 22.76 166 323866 8.54 ug/1 97 29) Azobenzen/ 1,2-Diphenylhyd 23.25 77 299719 7.12 ug/L # 93 31) N-Nitrosodiphenylamine 23.17 168 101218 6.00 ug/1 98 32) 4-Bromophenyl-phenylether 24.25 248 88279 8.96 ug/1 93

(#) = qualifier out of range (m) = manual integration REFA1 _D GCMS041Q M Pr Anr iq 1A.E7. 91 onno D 1

NYC-WTC_000043536