GCMS reference standard results, sample AE09450, May 2002

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Data File C:\HPCHEM\l\DATA\MAY0202\REF2.D Vial: 5 Acq On 2 May 2002 6:41 pm Operator: Sample GC/MS SCAN 4/19 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 3 8:14 2002 Quant Results File: GCMS0501.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed May 01 10:40:31 2002 Response via : Initial Calibration DataAcq Meth : GCMS0501

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.19 152 576769 40.00 ug/1 -0.02 10) Naphthalene-d8 15.83 136 2122210 40.00 ug/1 -0.02 17) Acenaphthene-diO 21.14 164 1137703 40.00 ug/1 -0.01 30) Phenanthrene-diO 25.58 188 1593909 40.00 ug/1 -0.01 38) Chrysene-dl2 33.65 240 965024 40.00 ug/1 -0.02 44) Perylene-dl2 37.87 264 613530 40.00 ug/1 -0.01

System Monitoring Compounds 28) TCMX 23.27 209 39030 7.05 ug/L -0.02 Spiked Amount 10.000 Recovery = 70.50%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.84 74 125544 7.96 ug/1 97 3) bis(2-Chloroethyl)ether 11.59 93 232976 11.39 ug/1 98 4) 1,3-Dichlorobenzene 12.09 146 179231 9.97 ug/1 98 5) 1,4-Dichlorobenzene 12.24 146 189198 9.63 ug/1 99 6) 1,2-Dichlorobenzene 12.75 146 185111 10.87 ug/1 100 7) 2,21-oxybis(1-Chloropropan 13.07 45 497613 11.77 ug/1 99 8) N-Nitroso-di-n-propylamine 13.46 70 177576 11.58 ug/1 99 9) Hexachloroethane 13.61 117 52086 7.06 ug/1 95 11) Nitrobenzene 13.87 77 185771 9.61 ug/1 97 12) Isophorone 14.52 82 499873 13.34 ug/1 98 13) bis(2-Chloroethoxy)methane 15.21 93 279695 11.76 ug/1 100 14) 1,2,4-Trichlorobenzene 15.71 180 153475 10.68 ug/1 99 15) Naphthalene 15.89 128 556531 12.53' ug/1 99 16) Hexachlorobutadiene 16.43 225 53999 8.18 ug/1 97 18) Hexachlorocyclopentadiene 18.63 237 24651 4.28 ug/1 97 19) 2-Chloronaphthalene 19.39 162 335114 13.34 ug/1 99 20) Dimethylphthalate 20.49 163 410922 12.85 ug/1 100 21) 2,6-Dinitrotoluene 20.70 165 48087 6.92 ug/1 95 22) Acenaphthylene 20.66 152 525042 11.61 ug/1 100 23) Acenaphthene 21.23 153 347565 13.10 ug/1 100 24) 2,4-Dinitrotoluene 21.87 165 49481 6.64 ug/1 96 25) Diethylphthalate 22.62 149 404646 13.95 ug/1 100 26) 4-Chlorophenyl-phenylether 22.77 204 174860 12.74 ug/1 99 27) Fluorene 22.75 166 381716 13.50 ug/1 99 29) Azobenzen/ 1,2-Diphenylhyd 23.24 77 439033 11.27 ug/L 98 31) N-Nitrosodiphenylamine 23.16 168 140814 13.32 ug/1 95 32) 4-Bromophenyl-phenylether 24.24 248 97255 12.56 ug/1 97 33) Hexachlorobenzene 24.68 284 119044 13.77 ug/1 99 34) Phenanthrene 25.65 178 501412 12.98 ug/1 99

(#) = qualifier out of range (m) = manual integration REF2.D GCMS0501.M Fri May 03 08:18:41 2002 Page 1

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