GCMS reference analysis results, DEP Box 25, May 1 2002

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Data File C:\HPCHEM\1\DATA\MAY0102\REF1.D Vial: 8 Acq On 1 May 2002 2:29 pm Operator: Sample gc/ms scan 4/18 Inst : 209 Mise Multiplr: 1.00 MS Integration Params: GOOFY.P Quant Time: May 2 11:38 2002 Quant Results File: GCMS0501.RES

Quant Method : C:\HPCHEM\1\METHODS\GCMS0501.M (RTE Integrator) Title : 209 625/TCLP calibration table Last Update : Wed May 01 10:40:31 2002 Response via : Initial Calibration DataAcqMeth : GCMS0501

Internal Standards R.T. Qlon Response Cone Units Dev(Min)

1) 1,4-Dichlorobenzene-d4 12.21 152 471474 40.00 ug/1 0.00 10) Naphthalene-d8 15.84 136 1748285 40.00 ug/1 0.00 17) Acenaphthene-diO 21.15 164 923146 40.00 ug/1 0.00 30) Phenanthrene-dlO 25.59 188 1319676 40.00 ug/1 0.00 38) Chrysene-dl2 33.65 240 893877 40.00 ug/1 -0.02 44) Perylene-dl2 37.87 264 549987 40.00 ug/1 0.00

System Monitoring Compounds 2 8) TCMX 23.29 209 36027 8.02 ug/L 0.00 Spiked Amount 10.000 Recovery = 80.20%

Target Compounds Qvalue 2) N-nitroso-dimethyl amine 5.86 74 151017 11.72 ug/1 96 3) bis(2-Chloroethyl )ether 11.60 93 297104 17.77 ug/1 98 4) 1,3-Dichlorobenzene 12.11 146 168214 11.45 ug/1 97 5) 1,4-Dichlorobenzene 12.25 146 184483 11.49 ug/1 99 6) 1,2-Dichlorobenzene 12.77 146 192766 13.85 ug/1 99 7) 2,21 -oxybis(1-Chloropropan 13.09 45 630794 18.25 ug/1 99 8) N-Nitroso-di-n-propylamine 13.47 70 234739 18.73 ug/1 98 9) Hexachloroethane 13.62 117 34939 5.79 ug/1 99 11) Nitrobenzene 13.88 77 267866 16.82 ug/1 97 12) Isophorone 14.53 82 471434 15.27 ug/1 99 13) bis(2-Chloroethoxy)methane 15.21 93 355214 18.13 ug/1 99 14) 1,2,4-Trichlorobenzene 15.73 180 157871 13.33 ug/1 99 15) Naphthalene 15.90 128 657137 17.95 ug/1 99 16) Hexachlorobutadiene 16.44 225 23978 4.41 ug/1 98 18) Hexachlorocyclopentadiene 18.64 237 4013 0.86 ug/1 96 19) 2-Chloronaphthalene 19.40 162 387633 19.02 ug/1 100 20) Dimethylphthalate 20.49 163 498340 19.20 ug/1 100 21) 2,6-Dinitrotoluene 20.71 165 93383 16.56 ug/1 99 22) Acenaphthylene 20.67 152 603045 16.44 ug/1 99 23) Acenaphthene 21.23 153 406943 18.91 ug/1 99 24) 2,4-Dinitrotoluene 21.87 165 107069 17.71 ug/1 100 25) Diethylphthalate 22.63 149 498986 21.20 ug/1 99 26) 4-Chlorophenyl-phenylether 22.78 204 197206 17.71 ug/1 99 27) Fluorene 22.75 166 457964 19.96 ug/1 100 29) Azobenzen/ 1,2-Diphenylhyd 23.24 77 568255 17.97 ug/L 98 31) N-Nitrosodiphenylamine 23.17 168 112577 12.87 ug/1 98 32) 4-Bromophenyl-phenylether 24.25 248 111061 17.32 ug/1 98 33) Hexachlorobenzene 24.68 284 131659 18.39 ug/1 97 34) Phenanthrene 25.65 178 618710 19.35 ug/1 100

(#) = qualifier out of range (m) = manual integration REFl.D GCMS0501.M Thu May 02 11:40:30 2002 Page 1

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